265671-59-8

Basic information

• Product Name: (3-bromo-1-phenylbut-3-enyloxy)diphenyl(trimethylsilyl)silane
• Synonyms: (3-bromo-1-phenylbut-3-enyloxy)diphenyl(trimethylsilyl)silane
• CAS NO: 265671-59-8
• Molecular Weight: 481.58
• Mol File: 265671-59-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3-bromo-1-phenylbut-3-enyloxy)diphenyl(trimethylsilyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: (3-bromo-1-phenylbut-3-enyloxy)diphenyl(trimethylsilyl)silane(265671-59-8)
• EPA Substance Registry System: (3-bromo-1-phenylbut-3-enyloxy)diphenyl(trimethylsilyl)silane(265671-59-8)

Safety Data

• Hazardous Substances Data: 265671-59-8(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 61211-96-9 1-chloro-1,1-diphenyl-2,2,2-trimethyldisilane 
• 87763-90-4 3-bromo-1-phenyl-but-3-en-1-ol 

Relevant articles and documents

Synthesis of biaryls by intramolecular radical aryl migration from silicon to carbon

(equation presented) A new method for the preparation of biaryls via intramolecular 1,5 aryl migration reaction from silicon in silyl ethers to aryl radicals is presented. Various readily available diphenylsilyl ethers can be used as substrates in this reaction. Functionalized aryl groups can also be transferred. The analogous 1,4 aryl migration reaction is less efficient.