265975-35-7

Basic information

• Product Name: 2,4,6-tri-tert-butyldimethylsilyloxybenzaldehyde
• Synonyms: 2,4,6-tri-tert-butyldimethylsilyloxybenzaldehyde
• CAS NO: 265975-35-7
• Molecular Weight: 496.91
• Mol File: 265975-35-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,4,6-tri-tert-butyldimethylsilyloxybenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6-tri-tert-butyldimethylsilyloxybenzaldehyde(265975-35-7)
• EPA Substance Registry System: 2,4,6-tri-tert-butyldimethylsilyloxybenzaldehyde(265975-35-7)

Safety Data

• Hazardous Substances Data: 265975-35-7(Hazardous Substances Data)

Upstream product

• 487-70-7 2,4,6-trihydroxybenzaldehyde 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 233751-75-2 3,5-bis((tert-butyldimethylsilyl)oxy)-2-hydroxybenzaldehyde 
• 121056-98-2 3,4,5‐tris(tert‐butyldimethylsilyloxy)benzoic acid 

Relevant articles and documents

Selective cleavage of tert-butyldimethylsilylethers ortho to a carbonyl group by ultrasound

A general method for the selective cleavage of tert- butyldimethylsilylethers ortho to a carbonyl group is established by sonication of a 0.1 M solution of the substrate in 1/1 (v/v) CH3OH/CCl4. Other phenolic tert-butyldimethylsilylethers are unaffected. This reaction performed on flavanoids is completed within 3 h and no special workup is required. Other substrates are also investigated and a mechanism is proposed. (C) 2000 Elsevier Science Ltd.