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Diastereoselektive Synthese neuartiger Mannich-Basen mittels Titanderivaten
Seebach, Dieter,Betschart, Claudia,Schiess, Martin
, p. 1593 - 1597 (1984)
Trichlorotitanium dialkylamino-alkoxides (2; titanates of N,O-hemiacetals) are generated either from the corresponding lithium alkoxides and titanium tetrachloride (Scheme I) or by addition of trichloro-dialkylamino-titanium to aldehydes.The electrophilic
