265987-36-8

Basic information

• Product Name: 1,4-(m-PhCB₁₀H₁₀C)2C₆H₄
• CAS NO: 265987-36-8
• Molecular Weight: 586.694
• Mol File: 265987-36-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-(m-PhCB₁₀H₁₀C)2C₆H₄(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-(m-PhCB₁₀H₁₀C)2C₆H₄(265987-36-8)
• EPA Substance Registry System: 1,4-(m-PhCB₁₀H₁₀C)2C₆H₄(265987-36-8)

Safety Data

• Hazardous Substances Data: 265987-36-8(Hazardous Substances Data)

Upstream product

• 392-56-3 Hexafluorobenzene 
• 16351-47-6 1-phenyl-1,7-dicarba-closo-dodecaborane⁽¹²⁾ 

Relevant articles and documents

Syntheses and reactions of some new C-pentafluorophenyl and tetrafluorophenylene carborane systems

The reaction of para-PhCB10H10CLi with excess C6F6 produced para-PhCB10H10CC6F5 (52%) and the tetrafluorophenylene bridged system 1,4-(para-PhCB10H10C)2C6F 4 (31%). The C-pentafluorophenyl compound para-PhCB10H10CC6F5 afforded good yields of 1,4-tetrafluorophenylene bridged carboranes with suitable nucleophilic reagents: 1-(para-PhCB10H10C)-4-(ortho-HCB10H 10C)C6F4 from ortho-HCB10H10CLi, 1-(para-PhCB10H10C)-4-HOC6F4 from KOH and 1-(para-PhCB10H10C)-4-EtOC6F4 from KOEt. Addition of the monolithiated carborane, meta-PhCB10H10CLi, to excess C6F6 produced meta-PhCB10H10CC6F5 (19%) and the two-cage carborane 1,4-(meta-PhCB10H10C)2C6F 4 (70%). Reactions of the novel C-pentafluorophenyl meta carborane, meta-PhCB10H10CC6F5, with nucleophiles, ortho-HCB10H10CLi and nBuLi, gave 1-(meta-PhCB10H10C)-4-(ortho-HCB10H 10C)C6F4 and 1-(meta-PhCB10H10C)-4-nBuC6F 4, respectively. The structure of 1-(para-PhCB10H10C)-4-EtOC6F4 was determined by a single crystal X-ray diffraction study.