26620-10-0Relevant academic research and scientific papers
Stereoselective Synthesis of (E)-1-Halo-2-arylselanylethylenes via Hydrozirconation of Arylselanylethynes
Zhu, Liu-Sheng,Huang, Zhi-Zhen,Huang, Xian
, p. 112 - 113 (2007/10/03)
Hydrozirconation of arylselanylethynes gives zirconium(iv) complexes, which are trapped with iodine or N-bromosuccinimide to afford (E)-1-halo-2-arylselanylethylenes.
Synthesis of Vinyl Selenides or Sulfides and Ketene Selenoacetals or Thioacetals by Nickel(II) Vinylation of Sodium Benzeneselenolate or Benzenethiolate
Cristau, H. J.,Chabaud, B.,Labaudiniere, R.,Christol, H.
, p. 875 - 878 (2007/10/02)
The substitution of bromine atom on a double bond by benzeneselenolate or benzenethiolate anions is catalyzed by the bis(pyridine)nickel bromide complex.Various alkenyl selenides or sulfides and seleno- or thio acetals are prepared in good to excellent yi
