26628-47-7Relevant academic research and scientific papers
Absorption, fluorescence, and acid-base equilibria of rhodamines in micellar media of sodium dodecyl sulfate
Obukhova, Elena N.,Mchedlov-Petrossyan, Nikolay O.,Vodolazkaya, Natalya A.,Patsenker, Leonid D.,Doroshenko, Andrey O.,Marynin, Andriy I.,Krasovitskii, Boris M.
supporting information, p. 138 - 144 (2016/07/21)
Rhodamine dyes are widely used as molecular probes in different fields of science. The aim of this paper was to ascertain to what extent the structural peculiarities of the compounds influence their absorption, emission, and acid-base properties under unified conditions. The acid-base dissociation (HR+???R?+?H+) of a series of rhodamine dyes was studied in sodium n-dodecylsulfate micellar solutions. In this media, the form R exists as a zwitterion R±. The indices of apparent ionization constants of fifteen rhodamine cations HR+ with different substituents in the xanthene moiety vary within the range of pKaapp?=?5.04 to 5.53. The distinct dependence of emission of rhodamines bound to micelles on pH of bulk water opens the possibility of using them as fluorescent interfacial acid–base indicators.
Intrinsically thermochromic fluorans
Azizian, Farid,Field, Amanda J.,Heron, B. Mark,Kilner, Colin
, p. 750 - 752 (2012/02/02)
A Suzuki coupling strategy has been employed to access a series of novel fluorans substituted with a phenolic moiety. These fluorans display good thermochromism in methyl stearate and obviate the need for traditional complex formulations containing acidic colour developers.
Palladium-catalysed amination of bromofluorans and an investigation of their thermochromic behaviour
Azizian, Farid,Field, Amanda J.,Griffiths, John,Heron, B. Mark
experimental part, p. 524 - 530 (2012/02/02)
The palladium-catalysed amination of readily accessible bromofluorans and bromobenzo[a]fluorans has been accomplished with a series of anilines and morpholine. The resulting aminofluorans generated intense black shades upon formulation in methyl stearate containing bisphenol A. The route provides an alternative approach to various amino substituted fluorans without the need of a series of individual diphenylamine intermediates.
