267007-27-2

Basic information

• Product Name: [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2]⁽¹⁺⁾*[PF₆]^(1-) = [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2][PF₆]
• Synonyms: [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2]⁽¹⁺⁾*[PF₆]^(1-) = [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2][PF₆]
• CAS NO: 267007-27-2
• Molecular Weight: 820.47
• Mol File: 267007-27-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2]⁽¹⁺⁾*[PF₆]^(1-) = [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2][PF₆](CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2]⁽¹⁺⁾*[PF₆]^(1-) = [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2][PF₆](267007-27-2)
• EPA Substance Registry System: [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2]⁽¹⁺⁾*[PF₆]^(1-) = [Pd(C₆H₄CH₂NH(CH₃)2)Cl(P(C₆H₅)2)2(CH₂)2][PF₆](267007-27-2)

Safety Data

• Hazardous Substances Data: 267007-27-2(Hazardous Substances Data)

Upstream product

• 7647-01-0 hydrogenchloride 

Downstream Products

• 19978-61-1 (1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II) 

Relevant articles and documents

Reaction of di-μ-dichloro-bis(N,N-dimethylbenzylamine-C2,N)dipalladium(II) with diphosphines. Six-membered ring complexes bearing spiro rings

Reactions of [Pd(C6H4CH2NMe2-C2,N)(μ-Cl)]2 with diphosphines (diphos) such as dppf (a), dpmf (b), dppm (c), dppe (d) and dppp (e) gave [PdCl(C6H4CH2NMe2-C2,N)]2(μ-diphos) (2). Complexes 2 (a, b, d and e) reacted with NaPF6 to produce chelate complexes [Pd(C6H4CH2NMe2-C2,N)(diphos-P,P')][PF6] (3), whereas 2c gave a six-membered ring complex [Pd2(C6H4CH2NMe2-C2,N)2(μ-Cl)(μ-dppm)][PF6] (4c) bearing two exocyclic rings shared by each palladium atom. This complex was regenerated to 2c by treatment with [NEt3(CH2Ph)]Cl. Treatment of 3 (a, d and e) with one equiv. of aq. HCl caused protonation at the coordinate nitrogen atom to yield [Pd(C6H4CH2NHMe2-C2)(Cl)(diphos-P,P')][PF6] (5) (a, d and e). Reaction of 4c with aq. HCl in a 1:1 molar ratio led to protonation at one C-N chelating ring to give [Pd2(Cl)(C6H4CH2NMe2-C2,N)(C6H4CH2NHMe2-C2)(μ-Cl)(μ-dppm)][PF6] (6c). The structures of 2a, 3e, 4c, 5a and 6c were confirmed by X-ray analyses. (C) 2000 Elsevier Science S.A.