267012-06-6

Basic information

• Product Name: methyl(4-methylphenyl)(3,3,3-trifluoropropyl)silanol
• Synonyms: methyl(4-methylphenyl)(3,3,3-trifluoropropyl)silanol
• CAS NO: 267012-06-6
• Molecular Weight: 248.32
• Mol File: 267012-06-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl(4-methylphenyl)(3,3,3-trifluoropropyl)silanol(CAS DataBase Reference)
• NIST Chemistry Reference: methyl(4-methylphenyl)(3,3,3-trifluoropropyl)silanol(267012-06-6)
• EPA Substance Registry System: methyl(4-methylphenyl)(3,3,3-trifluoropropyl)silanol(267012-06-6)

Safety Data

• Hazardous Substances Data: 267012-06-6(Hazardous Substances Data)

Upstream product

• 2374-14-3 1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane 
• 2417-95-0 p-tolyllithium 

Downstream Products

• 644-08-6 4-Methylbiphenyl 

Relevant articles and documents

Substituent effect of 3,3,3-trifluoropropyl group on organic silanols. Palladium-mediated Mizoroki-Heck type and cross-coupling reactions

The Mizoroki-Heck type reaction of methyl(phenyl)(3,3,3- trifluoropropyl)silanol (1a) with ethyl acrylate in the presence of Pd(OAc)2 (10 mol%) and Cu(OAc)2/LiOAc gave ethyl cinnamate in 70% yield. The palladium-catalyzed cross-coupl