2374-14-3Relevant articles and documents
ULTRAVIOLET ABSORPTION OF THE SILOXANE BOND IN THE REGION 186-220 nm
Kirichenko, E. A.,Ermakov, A. I.,Pimkin, N. I.,Kopylov, V. M.
, p. 1280 - 1283 (2007/10/02)
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Alfa Aesar
(L16680) 1,3,5-Trimethyl-1,3,5-tris(3,3,3-trifluoropropyl)cyclotrisiloxane, 97%
2374-14-3
5g
324.0CNY
Alfa Aesar
(L16680) 1,3,5-Trimethyl-1,3,5-tris(3,3,3-trifluoropropyl)cyclotrisiloxane, 97%
2374-14-3
25g
1162.0CNY
Alfa Aesar
(L16680) 1,3,5-Trimethyl-1,3,5-tris(3,3,3-trifluoropropyl)cyclotrisiloxane, 97%
2374-14-3
100g
3303.0CNY
Version: 1.0
Creation Date: Aug 11, 2017
Revision Date: Aug 11, 2017
Product name | 2,4,6-trimethyl-2,4,6-tris(3,3,3-trifluoropropyl)-1,3,5,2,4,6-trioxatrisilinane |
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Product number | - |
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Other names | Fluorosilicone trimer |
Identified uses | For industry use only. CBI,Intermediates |
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Uses advised against | no data available |
Emergency phone number | - |
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Service hours | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). |
More Details:2374-14-3 SDS
methyl(3,3,3-trifluoropropyl)dichlorosilane
A
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
B
2,4,6,8-tetramethyl-2,4,6,8-tetrakis-(3,3,3-trifluoro-propyl)-cyclotetrasiloxane
Conditions | Yield |
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With diethyl ether; water |
methyl(3,3,3-trifluoropropyl)dichlorosilane
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
Conditions | Yield |
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hydrolysis; |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethyltrisiloxane-1,5-diol
Conditions | Yield |
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With palladium on activated carbon; water; hydrogen In tetrahydrofuran at 25℃; for 144h; | 90.2% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
dimethylsilicon dichloride
C14H28F9NO3Si4
Conditions | Yield |
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Stage #1: 1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane; dimethylsilicon dichloride; 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone at 20℃; for 12h; Inert atmosphere; Stage #2: With ammonia In toluene at 5℃; for 6h; Cooling with ice; | 89.1% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
phenyllithium
methyl(phenyl)(3,3,3-trifluoropropyl)silanol
Conditions | Yield |
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In diethyl ether at 0 - 20℃; Alkylation; | 84% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
bis<4-(methacryloyloxy)butyl>tetramethyldisiloxane
Conditions | Yield |
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With trifluorormethanesulfonic acid In chloroform at 25℃; for 24h; | 81.5% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
Conditions | Yield |
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With trifluorormethanesulfonic acid In chloroform at 25℃; for 24h; | 80.3% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
p-tolyllithium
methyl(4-methylphenyl)(3,3,3-trifluoropropyl)silanol
Conditions | Yield |
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In diethyl ether Arylation; | 76% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
(E)-1-iodohept-1-ene
Conditions | Yield |
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Stage #1: (E)-1-iodohept-1-ene With n-butyllithium In diethyl ether; hexane at -78℃; for 1h; Stage #2: 1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane In diethyl ether at -78 - 20℃; | 75% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
2-naphthyllithium
Conditions | Yield |
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In diethyl ether at 0 - 20℃; Alkylation; | 74% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
(E)-2-phenylethenyllithium
methyl(E)-2-phenylethenyl(3,3,3-trifluoropropyl)silanol
Conditions | Yield |
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70% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
p-methoxyphenyllithium
4-methoxyphenyl(methyl)(3,3,3-trifluoropropyl)silanol
Conditions | Yield |
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In diethyl ether Arylation; | 69% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
naphthalen-1-yl-lithium
Conditions | Yield |
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In diethyl ether at 0 - 20℃; Alkylation; | 66% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
α-phenyl vinyllithium
phenyllithium
methyl(E)-2-phenylethenyl(3,3,3-trifluoropropyl)silanol
Conditions | Yield |
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In diethyl ether at 0 - 20℃; Alkylation; | 55% |
n-butyllithium
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
dimethylsilicon dichloride
Conditions | Yield |
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Stage #1: n-butyllithium; 1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane In tetrahydrofuran; toluene at 0 - 25℃; for 8h; Stage #2: dimethylsilicon dichloride With triethylamine In tetrahydrofuran; toluene at 20 - 25℃; for 3h; Stage #3: With water In tetrahydrofuran; toluene for 0.0833333h; | 47.8% |
Stage #1: n-butyllithium; 1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane In toluene at 0 - 25℃; for 8h; Stage #2: dimethylsilicon dichloride With triethylamine In toluene at 20 - 25℃; for 3h; | 47.8% |
Stage #1: n-butyllithium; 1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane In tetrahydrofuran; toluene at 0 - 25℃; for 8h; Stage #2: dimethylsilicon dichloride With triethylamine In tetrahydrofuran; toluene at 20 - 25℃; for 3h; | 47.8% |
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
acetic anhydride
1,5-Diacetoxy-1,3,5-trimethyl-1,3,5-tris-(3,3,3-trifluor-propyl)-trisiloxan
Conditions | Yield |
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With iron(III) chloride at 150℃; |
methyl(3,3,3-trifluoropropyl)dichlorosilane
A
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
B
2,4,6,8-tetramethyl-2,4,6,8-tetrakis-(3,3,3-trifluoro-propyl)-cyclotetrasiloxane
Conditions | Yield |
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With diethyl ether; water |
methyl(3,3,3-trifluoropropyl)dichlorosilane
1,3,5-tris(3,3,3-trifluoropropyl)-1,3,5-trimethylcyclotrisiloxane
Conditions | Yield |
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hydrolysis; |
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