26730-04-1

Basic information

• Product Name: Phenazine,2-methyl-10-oxide
• Synonyms: Phenazine,2-methyl-10-oxide
• CAS NO: 26730-04-1
• Molecular Formula: C13H10 N2 O
• Molecular Weight: 210.23
• Mol File: 26730-04-1.mol

Chemical Properties

• Boiling Point: 415.2°Cat760mmHg
• Flash Point: 204.9°C
• Appearance: /
• Density: 1.24g/cm³
• Vapor Pressure: 1.01E-06mmHg at 25°C
• Refractive Index: 1.665
• CAS DataBase Reference: Phenazine,2-methyl-10-oxide(CAS DataBase Reference)
• NIST Chemistry Reference: Phenazine,2-methyl-10-oxide(26730-04-1)
• EPA Substance Registry System: Phenazine,2-methyl-10-oxide(26730-04-1)

Safety Data

• Hazardous Substances Data: 26730-04-1(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H10N2O/c1-9-6-7-11-13(8-9)15(16)12-5-3-2-4-10(12)14-11/h2-8H,1H3

Upstream product

• 99-99-0 1-methyl-4-nitrobenzene 
• 273-09-6 benzofurazan 
• 123726-16-9 bis(4-methylphenyl)iodonium trifluoromethanesulfonate 
• 480-96-6 benzofurazan oxide 
• 88-74-4 2-nitro-aniline 
• 1016-94-0 2-methylphenazine 
• 62-53-3 aniline 
• 98-95-3 nitrobenzene 
• 106-49-0 p-toluidine 

Relevant articles and documents

Cu-Catalyzed π-Core Evolution of Benzoxadiazoles with Diaryliodonium Salts for Regioselective Synthesis of Phenazine Scaffolds

The Cu-catalyzed regioselective synthesis of phenazine N-oxides was realized from benzoxadiazoles and diaryliodonium salts. The process was initiated by the electrophilic arylation of benzoxadiazoles with diaryliodonium salts and followed by benzocyclization reactions. The further reduction of N-oxides in situ to phenazine scaffolds and deviation to organic fluorescent materials were readily accomplished.

A polysubstituted phenazine derivative and its oxide high-efficient preparation method (by machine translation)

The invention belongs to the technical field of chemical preparation of a polysubstituted phenazine derivative and its oxide high-efficient preparation method. The preparation method is added to the reactor in the diaryl expensive Iodized salt, benzo furazane, copper-based catalyst, replacing nitrogen after three times, adding solvent, finishing feeding the heating reaction; the end of the reaction, after cooling to room temperature after treatment, separating, purifying to obtain the phenazine oxide pure product; phenazine oxide product can be further reduction, after treatment, separation, purification phenazine derivatives. The present invention provides a multi-substituted phenazine derivative and its oxide process is reasonable, can be synthesized by other method is difficult to synthesis of the asymmetric multi-substituted phenazine derivatives, the preparation method is simple, high yield, the product is easy to purification. (by machine translation)