267432-89-3

Upstream product

• 76329-07-2 4-methyloct-7-en-1-yn-4-ol 
• 109-49-9 5-Hexen-2-one 
• 1379673-93-4 5-(methoxymethoxy)-5-methyloct-1-en-7-yne 
• 81036-84-2 3-bromocyclohex-2-en-1-one ethylene ketal 
• 68433-92-1 3-Vinyl-3-cyclohexen-1-one 
• 7680-19-5 5-Dioxolane-1-vinylcyclohex-1-ene 
• 107-30-2 chloromethyl methyl ether 
• 267432-87-1 1-Methyl-3-vinyl-3-cyclohexen-1-ol 

Downstream Products

• 7351-08-8 tetrangomycin 
• 131919-12-5 8-O-methyltetrangomycin 

Relevant academic research and scientific papers

A unified strategy for the syntheses of angucyclinone antibiotics: Total syntheses of tetrangulol, kanglemycin M, X-14881-E, and anhydrolandomycinone

A unified strategy for the syntheses of angucyclinone antibiotics was developed utilizing sequential intramolecular enyne metathesis, Diels-Alder/aromatization, photooxygenation, and one-pot elimination/ aromatization reactions. The diversity in this sequ

Enantioselective diels-alder approach to C-3-oxygenated angucyclinones from (SS)-2-(p-Tolylsulfinyl)-1,4-naphthoquinone

Chiral racemic vinylcyclohexenes 2, bearing oxygenated substituents and/or a methyl group at the C-5 position of the cyclohexene ring, were submitted to Diels-Alder reactions with enantiomerically pure (SS)-(2-p- tolylsulfinyl)-1,4-naphthoquinone [(+)-1].