26776-29-4

Basic information

• Product Name: POLY(SEBACIC ANHYDRIDE)
• Synonyms: POLY(SEBACIC ANHYDRIDE);decanedioicacid,homopolymer;sebacic acid homopolymer;Poly(sebacic acid)
• CAS NO: 26776-29-4
• Molecular Formula: C10H18O4
• Molecular Weight: 202.24752
• Mol File: 26776-29-4.mol
• Article Data: 67

Chemical Properties

• Melting Point: 80 °C(lit.)
• Boiling Point: 374.3°Cat760mmHg
• Flash Point: 198.3°C
• Appearance: /
• Density: 1 g/mL at 25 °C(lit.)
• CAS DataBase Reference: POLY(SEBACIC ANHYDRIDE)(CAS DataBase Reference)
• NIST Chemistry Reference: POLY(SEBACIC ANHYDRIDE)(26776-29-4)
• EPA Substance Registry System: POLY(SEBACIC ANHYDRIDE)(26776-29-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• Hazardous Substances Data: 26776-29-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H18O4/c11-9(12)7-5-3-1-2-4-6-8-10(13)14/h1-8H2,(H,11,12)(H,13,14)

Upstream product

• 1577-55-5 octadec-9-ene-1,12-diol 
• 32779-22-9 10,11-dihydroxyundecanoic acid 
• 5714-92-1 deca-4,6-diynedioic acid 
• 693-55-0 monoethyl sebacate 
• 112-47-0 1,10-Decanediol 
• 106-79-6 dimethyl sebacate 
• 1871-96-1 sebaconitrile 
• 56-23-5 tetrachloromethane 
• 1679-53-4 10-hydroxydecanoic acid 
• 16630-91-4 2-methylheptanal 
• 7732-18-5 water 
• 141-22-0 Ricinoleic acid 
• 3386-63-8 10-Octadecenoic acid methyl ester 
• 10544-72-6 dinitrogen tetraoxide 

Downstream Products

• 4629-03-2 1,10-di(piperidin-1-yl)decane-1,10-dione 
• 115291-39-9 decanedioic acid di-m-tolyl ester 
• 95699-74-4 decanedioic acid di-o-tolyl ester 
• 35658-49-2 sebacic acid bis-(phenylhydrazide) 
• 6712-10-3 10-oxo-10-phenyldecanoic acid 
• 273410-65-4 zinc(II)sebacate*(hydrazine) 
• 159350-38-6 10-(2,5-dioxopyrrolidin-1-yloxy)-10-oxodecanoic acid 
• 10355-50-7 divinyl sebacate 

Relevant articles and documents

A direct synthesis of carboxylic acidsviaplatinum-catalysed hydroxycarbonylation of olefins

The platinum-catalysed hydroxycarbonylation of olefins is reported for the first time. Using a combination of PtCl2/2,2′-bis(tert-butyl(pyridin-2-yl)phosphanyl)-1,1′-binaphthalene (Neolephos) in the presence of sulfuric acid [0.6 M] in acetic acid selective carbonylation of terminal aliphatic olefins proceeds to good yields and selectivities to the corresponding carboxylic acids. Comparing the reactivity of different butenes (iso- andn-butenes), the terminal olefin can be selectively carbonylated.

Synthesis of Dicarboxylic Acids from Aqueous Solutions of Diols with Hydrogen Evolution Catalyzed by an Iridium Complex

A catalytic system for the synthesis of dicarboxylic acids from aqueous solutions of diols accompanied by the evolution of hydrogen was developed. An iridium complex bearing a functional bipyridonate ligand with N,N-dimethylamino substituents exhibited a high catalytic performance for this type of dehydrogenative reaction. For example, adipic acid was synthesized from an aqueous solution of 1,6-hexanediol in 97 % yield accompanied by the evolution of four equivalents of hydrogen by the present catalytic system. It should be noted that the simultaneous production of industrially important dicarboxylic acids and hydrogen, which is useful as an energy carrier, was achieved. In addition, the selective dehydrogenative oxidation of vicinal diols to give α-hydroxycarboxylic acids was also accomplished.

PROCESS FOR THE CO-PRODUCTION OF LONG CHAIN AMINO ACIDS AND DIBASIC ACIDS

There is disclosed a process for the co-production of long chain ω-amino acid and long chain dibasic acid, comprising: (1) reacting long chain ketoacid derivative with hydroxylamine or subjecting ketoacid derivative to an ammoximation to yield oxime derivative; (2) subjecting oxime derivative to Beckmann rearrangement to yield a mixture of mixed amide derivatives; (3) hydrolyzing the mixed amide derivatives to produce long chain ω-amino acid and long chain dibasic acid.