26922-84-9

Basic information

• Product Name: methyl 4-O-benzyl-3-deoxy-α-D-ribo-hexopyranoside
• Synonyms: methyl 4-O-benzyl-3-deoxy-α-D-ribo-hexopyranoside
• CAS NO: 26922-84-9
• Molecular Weight: 268.31
• Mol File: 26922-84-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 4-O-benzyl-3-deoxy-α-D-ribo-hexopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-O-benzyl-3-deoxy-α-D-ribo-hexopyranoside(26922-84-9)
• EPA Substance Registry System: methyl 4-O-benzyl-3-deoxy-α-D-ribo-hexopyranoside(26922-84-9)

Safety Data

• Hazardous Substances Data: 26922-84-9(Hazardous Substances Data)

Upstream product

• 1352406-79-1 methyl 2-O-(p-methoxybenzyl)-4,6-O-benzylidene-3-deoxy-α-D-glucopyranoside 
• 1352406-78-0 methyl 2-O-[(1,1-dimethylethyl)dimethylsilyl]-4,6-O-benzylidene-3-deoxy-α-D-glucopyranoside 
• 65556-00-5 methyl 4,6-di-O-benzylidene-2,3-di-O-tosyl-α-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 65530-28-1 methyl 4,6-O-benzylidene-3-deoxy-α-D-glucopyranoside 

Downstream Products

• 581060-34-6 methyl 4-O-benzyl-3,6-dideoxy-6-iodo-α-D-ribo-hexopyranoside 
• 1352406-80-4 methyl 4-O-benzyl-3-deoxy-α-D-gluco-hexodialdo-1,5-pyranoside 
• 100-51-6 benzyl alcohol 
• 905312-31-4 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'R)-2'-(4-methoxybenzyloxy)-1'-(p-toluenesulfonyloxy)propyl]-4-vinylcyclohexan-2-ol 
• 581060-41-5 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-2-methoxymethyloxy-3-[(R)-1'-(p-toluenesulfonyloxy)-2'-oxopropyl]-4-vinylcyclohexane 
• 581060-40-4 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'R)-2'-hydroxy-1'-(p-toluenesulfonyloxy)propyl]-2-methoxymethyloxy-4-vinylcyclohexane 
• 581060-38-0 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'R)-1'-hydroxy-2'-(4-methoxybenzyloxy)propyl]-4-vinylcyclohexan-2-ol 
• 581060-32-4 (2S,3R,4R,6S)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-2-[(1'R,2'R)-1'-hydroxy-2'-(4-methoxybenzyloxy)propyl]-3-vinylcyclohexan-1-one 
• 581060-37-9 (2R,3R,4R,6S)-6-benzyloxy-4-(tert-butyldimethylsilyloxy)-2-[(1'S,2'S)-1'-hydroxy-2'-(4-methoxybenzyloxy)propyl]-3-vinylcyclohexan-1-one 
• 581060-36-8 (2S,4R)-2-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-hydroxy-cyclohexan-1-one 
• 581060-33-5 (4R,6S)-6-benzyloxy-4-[(tert-butyldimethylsilyl)oxy]-2-cyclohexenone 
• 905312-28-9 methyl 4-O-benzyl-2-O-(tert-butyldimethylsilyl)-3,6-dideoxy-6-iodo-α-D-ribo-hexopyranoside 
• 581060-35-7 methyl 4-O-benzyl-2-O-(tert-butyldimethylsilyl)-3,6-dideoxy-α-D-erythro-hex-5-enopyranoside 

Relevant articles and documents

Synthesis of locked pyranosyl nucleic acid (LpNA)

A new locked pyranosyl nucleoside was synthesized by phenylsulfinyl- assisted chemistry. The novel building block was inserted into oligonucleotides and provides new insight on conformational restricted pyranosyl nucleosides on duplex formation

Regioselectivity of Reductive Cleavage of Methyl 4,6-O-Benzylidene-3-deoxyhexopyranosides Containing Fluorine at the 2- or 3-Position with LiAlH4-AlCl3

Reductive ring-opening reactions of the 4,6-O-benzylidene derivatives of methyl 3-deoxy-β-D-arabino-, 3-deoxy-α-D-ribo-, and 2-O-benzyl-3-deoxy-α-D-ribo-hexopyranosides with LiAlH4 and AlCl3 in the molar ratio of 4:4 gave the 4- and 6-O-benzyl derivatives