581060-33-5

Basic information

• Product Name: 2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-(phenylmethoxy)-, (4R,6S)-
• CAS NO: 581060-33-5
• Molecular Formula: C19H28O3Si
• Molecular Weight: 332.515
• Mol File: 581060-33-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-(phenylmethoxy)-, (4R,6S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-(phenylmethoxy)-, (4R,6S)-(581060-33-5)
• EPA Substance Registry System: 2-Cyclohexen-1-one, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-(phenylmethoxy)-, (4R,6S)-(581060-33-5)

Safety Data

• Hazardous Substances Data: 581060-33-5(Hazardous Substances Data)

Upstream product

• 905312-28-9 methyl 4-O-benzyl-2-O-(tert-butyldimethylsilyl)-3,6-dideoxy-6-iodo-α-D-ribo-hexopyranoside 
• 581060-35-7 methyl 4-O-benzyl-2-O-(tert-butyldimethylsilyl)-3,6-dideoxy-α-D-erythro-hex-5-enopyranoside 
• 581060-34-6 methyl 4-O-benzyl-3,6-dideoxy-6-iodo-α-D-ribo-hexopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 65530-28-1 methyl 4,6-O-benzylidene-3-deoxy-α-D-glucopyranoside 
• 581060-36-8 (2S,4R)-2-benzyloxy-4-(tert-butyldimethylsilyloxy)-5-hydroxy-cyclohexan-1-one 
• 26922-84-9 methyl 4-O-benzyl-3-deoxy-α-D-ribo-hexopyranoside 

Downstream Products

• 1268868-53-6 (1R,4R,6S)-6-benzyloxy-4-[(tert-butyldimethylsilyl)oxy]-1-(2,3-dimethoxyphenyl)-2-cyclohexen-1-ol 
• 1268868-57-0 (1S,4R,6S)-6-benzyloxy-4-[(tert-butyldimethylsilyl)oxy]-1-(2,3-dimethoxyphenyl)-2-cyclohexen-1-ol 
• 581060-39-1 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'R)-2'-(4-methoxybenzyloxy)-1'-(p-toluenesulfonyloxy)propyl]-2-methoxymethyloxy-4-vinylcyclohexane 
• 905312-31-4 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'R)-2'-(4-methoxybenzyloxy)-1'-(p-toluenesulfonyloxy)propyl]-4-vinylcyclohexan-2-ol 
• 581060-42-6 (1R,2R,3S,4S,6R)-4-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-3-methoxymethoxy-2-[(R)-2-oxo-1-(toluene-4-sulfonyloxy)-propyl]-cyclohexanecarboxylic acid 
• 581060-41-5 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-2-methoxymethyloxy-3-[(R)-1'-(p-toluenesulfonyloxy)-2'-oxopropyl]-4-vinylcyclohexane 
• 581060-44-8 (3S,4R,4aS,5S,6S,8R,8aR)-6-benzyloxy-8-(tert-butyldimethylsilyloxy)-5-methoxymethyloxy-3-methyl-4-(p-toluenesulfonyloxy)-perhydroisochroman-1-one 
• 581060-40-4 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'R)-2'-hydroxy-1'-(p-toluenesulfonyloxy)propyl]-2-methoxymethyloxy-4-vinylcyclohexane 
• 581060-38-0 (1S,2S,3S,4R,5R)-1-benzyloxy-5-(tert-butyldimethylsilyloxy)-3-[(1'R,2'R)-1'-hydroxy-2'-(4-methoxybenzyloxy)propyl]-4-vinylcyclohexan-2-ol 
• 581060-46-0 N-benzyloxycarbonyl-(-)-actinobolin 
• 581060-31-3 (3S,4S,5S,6S,8R,9R,10S)-4-azido-6-benzyloxy-8-(tert-butyldimethylsilyloxy)-5-methoxymethyloxy-3-methyl-perhydroisochroman-1-one 
• 905312-38-1 (3S,4S,4aS,5S,6S,8R,8aR)-4-Azido-6-benzyloxy-8-hydroxy-5-methoxymethoxy-3-methyl-octahydro-isochromen-1-one 
• 581060-45-9 (3S,4S,5S,6S,10S)-4-azido-6-benzyloxy-5,8-dihydroxy-3-methyl-5,6,7,4a-tetrahydroisochroman-1-one 
• 905312-35-8 (1R,2R,3S,4S,6R)-4-Benzyloxy-6-(tert-butyl-dimethyl-silanyloxy)-2-[(1R,2R)-2-(4-methoxy-benzyloxy)-1-(toluene-4-sulfonyloxy)-propyl]-3-methoxymethoxy-cyclohexanecarboxylic acid 

Relevant articles and documents

Total synthesis of actinobolin from d-glucose by way of the stereoselective three-component coupling reaction

The total synthesis of (-)-actinobolin 3, an antipode of the natural product, starting from d-glucose is described. A three-component coupling reaction of functionalized cyclohexenone (+)-6 derived from d-glucose by way of Ferrier's carbocyclization react