2697-37-2

Usage

Physical state

Colorless liquid

Functional groups

Chloromethyl group and ethenyl group

Structure

Attached to a 1,3-dioxolane ring

Usage

Intermediate in the synthesis of other compounds
Pharmaceutical synthesis
Agrochemical synthesis

Industrial applications

Production of polymers and as a solvent

Hazardous properties

Harmful if swallowed, inhaled, or in contact with the skin

Potential health effects

Respiratory and skin irritation

Upstream product

• 96-24-2 3-monochloro-1,2-propanediol 
• 107-02-8 acrolein 
• 106-89-8 epichlorohydrin 

Relevant academic research and scientific papers

PERFLUORINATED RESINSULFONIC ACID - A CATALYST FOR CERTAIN ORGANIC REACTIONS.

The purpose of this work was to examine the possibility of using, as a catalyst in certain organic reactions, the perfluorinated resinsulfonic acid F-4SK in the H form, which is an analog of the perfluorinated resinsulfonic acid Nafion-H. To compare catalyst activity of the perfluorinated resinsulfonic acid in decomposition of cumene hydroperoxide, CHP was also decomposed in presence of KU-2 resin. It was found that during repeated use over a period of 150 h the activity of KU-2 catalyst under analogous conditions fell by 4-6%. During the same time the activity of the perfluorinated resinsulfonic acid remained unchanged. It is also known that the presence of a strong acid in the reaction mixture causes formation of by-products, namely the products of condensation of phenol with acetone and dimethylphenylcarbinol, and of dehydration of dimethylphenylcarbinol, with formation of alpha -methylstyrene and products of greater complexity.

SYNTHESIS OF DERIVATIVES OF 1,4-DIOXOLANE FROM α,β-UNSATURATED ALDEHYDES AND INVESTIGATION OF THEIR PROPERTIES

The corresponding substituted 1,3-dioxolanes were obtained by the reaction of propenal, 2-butenal, and 3-phenylpropenal with 3-chloro-, 3-(2-chloroethoxy)-, 3-(2-chloro-1-chloromethylethoxy)-, and 3-(2-propenyloxy)-1,2-propanediol.Their bromination and th

FORMATION DE DIOXOLANNES A PARTIR DE L'EPICHLORHYDRINE DU GLYCEROL. HYDROLYSE AISEE DE DIOXOLANNES PAR LE TOSYLATE DE PYRIDINIUM

We described a versatile synthesis of dioxolanne from 1-chlor 2,3-epoxypropane epichlorhydrine and different carbonyl compounds in presence of activated montmorillonite which is easily eliminated after the reaction.The hydrolysis was performed in mild conditions with pyridinium p-toluene sulfonate.