2702-32-1

Basic information

• Product Name: N-cyclohexyl-3-nitrobenzamide
• Synonyms: N-cyclohexyl-3-nitrobenzamide
• CAS NO: 2702-32-1
• Molecular Formula: C₁₃H₁₆N₂O₃
• Molecular Weight: 248.27774
• Mol File: 2702-32-1.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N-cyclohexyl-3-nitrobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-cyclohexyl-3-nitrobenzamide(2702-32-1)
• EPA Substance Registry System: N-cyclohexyl-3-nitrobenzamide(2702-32-1)

Safety Data

• Hazardous Substances Data: 2702-32-1(Hazardous Substances Data)

Upstream product

• 99-61-6 3-nitro-benzaldehyde 
• 108-91-8 cyclohexylamine 
• 99-08-1 1-methyl-3-nitrobenzene 
• 121-92-6 3-nitrobenzoic acid 
• 931-53-3 Cyclohexyl isocyanide 
• 13277-62-8 m-nitrobenzoyl bromide 
• 121-90-4 m-nitrobenzoic acid chloride 
• 585-79-5 m-nitrobromobenzene 
• 538-75-0 dicyclohexyl-carbodiimide 

Downstream Products

• 90234-18-7 C₁₅H₂₃N₃O₃S 
• 77201-15-1 3-amino-benzoic acid cyclohexylamide 

Relevant articles and documents

CuO-decorated magnetite-reduced graphene oxide: a robust and promising heterogeneous catalyst for the oxidative amidation of methylarenes in waterviabenzylic sp3C-H activation

A magnetite-reduced graphene oxide-supported CuO nanocomposite (rGO/Fe3O4-CuO) was preparedviaa facile chemical method and characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), UV-vis spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS), Brunauer-Emmett-Teller (BET) analysis, vibrating-sample magnetometry (VSM), and thermogravimetric (TG) analysis. The catalytic activity of the rGO/Fe3O4-CuO nanocomposite was probed in the direct oxidative amidation reaction of methylarenes with free amines. Various aromatic and aliphatic amides were prepared efficiently at room temperature from cheap raw chemicals usingtert-butyl hydroperoxide (TBHP) as a “green” oxidant and low-toxicity TBAI in water. This method combines the oxidation of methylarenes and amide bond formation into a single operation. Moreover, the synthesized nanocomposites can be separated from the reaction mixtures using an external magnet and reused in six consecutive runs without a noticeable decrease in the catalytic activity.

A novel approach for the synthesis of aryl amides

A novel and highly efficient approach for the synthesis of aryl amides in high yields by the reaction of carboxylic acids and isocyanides in methanol at ambient temperature is reported.

A mild and efficient reaction for conversion of carboxylic acids into acid bromides with ethyl tribromoacetate/triphenylphosphine under acid-free conditions

Acid bromides were prepared efficiently from carboxylic acids with readily available ethyl tribromoacetate and triphenylphosphine at room temperature under neutral conditions. The present process is applicable to the preparation of various acid bromides from aromatic and aliphatic carboxylic acids. Aromatic carboxylic acids were found to be more reactive than aliphatic carboxylic acids under reaction conditions.