270258-27-0Relevant academic research and scientific papers
Total synthesis of phytophthora mating hormone α1
Wang, Shun-Yi,Song, Ping,Chan, Li-Yan,Loh, Teck-Peng
supporting information; experimental part, p. 5166 - 5169 (2011/02/25)
Total synthesis of Phytophthora mating hormone α1 (1) has been demonstrated. The required stereochemistries (methyl) are achieved by applying CuI-(S)-Tol-BINAP-catalyzed conjugate addition of Grignard reagents to α,β-unsaturated esters.
Pheromone synthesis, CC: Synthesis of (S)-9-methylgermacrene-B, the male-produced sex pheromone of the sandfly Lutzomyia longipalpis from Lapinha, Brazil, and its (R)-isomer
Kurosawa, Satoshi,Mori, Kenji
, p. 955 - 962 (2007/10/03)
Both the enantiomers of 9-methylgermacrene-B (1) were synthesized from the enantiomers of methyl 3-hydroxy-2-methylpropanoate (2). The male-produced sex pheromone of the sandfly Lutzomyia longipalpis (the vector of the protozoan parasite Leishmania chagas
9-Methylgermacrene-B is confirmed as the sex pheromone of the sandfly Lutzomyia longipalpis from Lapinha, Brazil, and the absolute stereochemistry defined as S
Hamilton, J. Gordon C.,Hooper, Antony M.,Ibbotson, Helen C.,Kurosawa, Satoshi,Mori, Kenji,Muto, Shin-Etsu,Pickett, John A.
, p. 2335 - 2336 (2007/10/03)
The structure of the sex pheromone produced by the male sandfly Lutzomyia longipalpis, from the Lapinha Cave (Minas Gerais State) region of Brazil, previously proposed tentatively as the novel homosesquiterpene 9- methylgermacrene-B, is confirmed and the
