112057-64-4Relevant academic research and scientific papers
Tunable P-Chiral Bisdihydrobenzooxaphosphole Ligands for Enantioselective Hydroformylation
Tan, Renchang,Zheng, Xin,Qu, Bo,Sader, C. Avery,Fandrick, Keith R.,Senanayake, Chris H.,Zhang, Xumu
supporting information, p. 3346 - 3349 (2016/07/26)
Air-stable and tunable chiral bisdihydrobenzooxaphosphole ligands (BIBOPs) were employed in rhodium-catalyzed asymmetric hydroformylation of various terminal olefins with excellent conversions (>99%), moderate-to-excellent enantioselectivities (up to 95:5 er), and branched to linear ratios (b:l) of up to 400.
The efficient desymmetrization of glycerol using scaffolding catalysis
Giustra, Zachary X.,Tan, Kian L.
supporting information, p. 4370 - 4372 (2013/06/05)
Glycerol is an ideal building block for the synthesis of complex molecules, because it is inexpensive and highly functionalized. We report the desymmetrization of glycerol through silyl transfer, using a chiral organic catalyst in high yield and enantioselectivity.
Catalytic, efficient, and syn-selective construction of deoxypolypropionates and other chiral compounds via Zr-catalyzed asymmetric carboalumination of allyl alcohol
Liang, Bo,Novak, Tibor,Tan, Ze,Negishi, Ei-Ichi
, p. 2770 - 2771 (2007/10/03)
An efficient, syn-selective, all catalytic asymmetric protocol for the synthesis of α,ω-diheterofunctional deoxypolypropionates via Zr-catalyzed asymmetric carboalumination (ZACA reaction) was developed. The success of the method critically hinges on the
