27126-30-3Relevant academic research and scientific papers
Reduction of Nitroarenes to Anilines with a Benzothiazoline: Application to Enantioselective Synthesis of 2-Arylquinoline Derivatives
Miyagawa, Masamichi,Yamamoto, Ryota,Kobayashi, Nanako,Akiyama, Takahiko
, p. 499 - 502 (2019/02/26)
The metal-free reduction of nitroarenes to aniline derivatives was accomplished in a short time by using a benzothiazoline as the hydrogen donor in combination with a Bronsted acid. An enantioselective synthesis of 2-arylquinolines was achieved by using 1-aryl-3-(2-nitrophenyl)propan-1-ones as starting materials and a combination of a benzothiazoline and a chiral phosphoric acid.
Selective reductive amination of aldehydes from nitro compounds catalyzed by molybdenum sulfide clusters
Pedrajas,Sorribes,Junge,Beller,Llusar
supporting information, p. 3764 - 3768 (2017/08/21)
Secondary amines are selectively obtained from low value starting materials using hydrogen and a non-noble metal-based catalyst. The reductive amination of aldehydes from nitroarenes or nitroalkanes is efficiently catalyzed by a well-defined diamino molybdenum sulfide cluster in a one-pot homogeneous reaction. The integrity of the molecular cluster catalyst is preserved along the process.
Microwave-accelerated methodology for the direct reductive amination of aldehydes
Kangasmetsae, Jussi J.,Johnson, Tony
, p. 5653 - 5655 (2007/10/03)
(Chemical Equation Presented) An improved procedure for the direct reductive amination of aldehydes was developed which uses dibutyltin dichloride as catalyst in the presence of phenylsilane as reductant. Rapid reaction is promoted by the use of microwave conditions with anilines, secondary and primary amines being suitable reactants.
