27147-18-8Relevant academic research and scientific papers
N-Heterocyclic carbene catalyzed oxidative stannylation of aldehydes: A facile entry to organotin(IV) carboxylates
Reddi, Rambabu N.,Malekar, Pushpa V.,Sudalai, Arumugam
, p. 2679 - 2681 (2013/06/05)
A simple protocol is described for the oxidative transformation of aldehydes to the corresponding organotin(IV) carboxylates in high yields (up to 90%) that utilizes atmospheric O2 as the sole oxidant, N-heterocyclic carbene as catalyst (at 10 mol %), and tributyl tin chloride as stannylating agent. The uniqueness of the reaction lies in the direct conversion of aldehydes to the corresponding organotin(IV) carboxylates via stannylation of carboxylic acids, generated from the reaction of a Breslow intermediate with O2.
Synthesis, characterization and in vitro antitumour activity of triphenyl- and tri-n-butyltin benzoates, phenylacetates and cinnamates
Willem, Rudolph,Bouhdid, Abdeslam,Mahieu, Bernard,Ghys, Laurent,Biesemans, Monique,Tiekink, Edward R.T.,De Vos, Dick,Gielen, Marcel
, p. 151 - 158 (2007/10/03)
Spectroscopic, structural and antitumour properties of triphenyltin and tri-n-butyltin benzoates, phenylacetates and cinnamates are compared with those of their corresponding pentafluorophenyl analogues.
