27165-87-3Relevant academic research and scientific papers
Synthetic study and structure of cage-type cyclophane C36H36S6
Takemura, Hiroyuki,Nagaoka, Maiko,Kawasaki, Chihiro,Tokumoto, Kasumi,Tobita, Noriko,Takano, Yuki,Iwanaga, Tetsuo
, p. 1066 - 1070 (2017)
A cage compound was synthesized in order to investigate the structure and cation-π interactions of the metal ion complex. The multi-step synthesis was achieved starting from trimesic acid triethyl ester. In solution, a completely symmetrical structure that was anticipated by the molecular design was observed by 1H and 13C NMR spectroscopy. However, in the solid state, X-ray crystallographic analysis revealed that the compound had a collapsed structure.
