27165-88-4

Basic information

• Product Name: Tetracyclo[6.6.2.13,13.16,10]octadeca-1,3(17),6,8,10(18),13-hexaene
• Synonyms: [2.2.2](1,3,5)Cyclophane;Tetracyclo[6.6.2.13,13.16,10]octadeca-1,3(17),6,8,10(18),13-hexaene
• CAS NO: 27165-88-4
• Molecular Formula: C₁₈H₁₈
• Molecular Weight: 234.33552
• Mol File: 27165-88-4.mol
• Article Data: 6

Chemical Properties

• Boiling Point: 351.7°C at 760 mmHg
• Flash Point: 178.1°C
• Appearance: /
• Density: 1.1g/cm³
• Vapor Pressure: 8.19E-05mmHg at 25°C
• Refractive Index: 1.624
• CAS DataBase Reference: Tetracyclo[6.6.2.13,13.16,10]octadeca-1,3(17),6,8,10(18),13-hexaene(CAS DataBase Reference)
• NIST Chemistry Reference: Tetracyclo[6.6.2.13,13.16,10]octadeca-1,3(17),6,8,10(18),13-hexaene(27165-88-4)
• EPA Substance Registry System: Tetracyclo[6.6.2.13,13.16,10]octadeca-1,3(17),6,8,10(18),13-hexaene(27165-88-4)

Safety Data

• Hazardous Substances Data: 27165-88-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C18H18/c1-2-14-9-17-5-3-15-7-13(1)8-16(11-15)4-6-18(10-14)12-17/h7-12H,1-6H2

Upstream product

• 18226-42-1 1,3,5-Tris(bromomethyl)benzene 
• 27165-87-3 2,11,20-trithia<3₃> (1,3,5)-cyclophane 
• 27313-56-0 <2.2.2>(1,3,5)Cyclophan-1,9,17-trien 
• 127395-53-3 <3.3.3>(1,3,5)Cyclophane-2,11,20-trione 
• 27341-04-4 2,11,20-Trithia<3.3.3><1.3.5>cyclophan-trisulfon 

Downstream Products

• 42053-19-0 5,13-dimethyl[2.2]metacyclophane 
• 10549-25-4 2,7-dimethyl-4,5,9,10-tetrahydropyrene 
• 62941-04-2 2,7-dimethyl-4,5-dihydropyrene 
• 127699-77-8 13-Methyl-6-phenylsulfanylmethyl-tricyclo[9.3.1.1^4,8]hexadeca-1⁽¹⁴⁾,4,6,8⁽¹⁶⁾,11⁽¹⁵⁾,12-hexaene 
• 15679-24-0 2,9-dimethylpyrene 

Relevant articles and documents

EINE EINFACHE SYNTHESE VON /2n/CYCLOPHANEN

/2n/cyclophanes are prepared in a one-step process from bromomethyl benzenes and (Ph3P)2Ni(C2H4).

Further validation of the structure of Boekelheide's novel C18H24 hydrocarbon

Structure of the novel C18H24-cage hydrocarbon 5, described by Boekelheide and Hollins from 3> (1,3,5)-cyclophane 6 has been verified through its diagnostic 13C NMR data.

Thermally induced reorganisation of [23] (1,3,5)cyclophane

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SYN-5,13-DIMETHYLMETACYCLOPHANE. SYNTHESIS, SPECTRA AND THERMAL STABILITY

The title compound was synthesized in 3 steps from trithia3>(1,3,5)cyclophane.Activation parameters for its change to the anti conformer as well as its NMR, IR and UV spectra were secured.