27190-70-1

Basic information

• Product Name: Benzene, 1-ethyl-3-(trifluoromethyl)-
• Synonyms: m-Trifluormethyl-ethylbenzol;Benzene,1-ethyl-3-(trifluoromethyl);3-ethyl benzotrifluoride
• CAS NO: 27190-70-1
• Molecular Formula: C9H9F3
• Molecular Weight: 174.166
• Mol File: 27190-70-1.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 146.4±35.0 °C(Predicted)
• Density: 1.118±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzene, 1-ethyl-3-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-ethyl-3-(trifluoromethyl)-(27190-70-1)
• EPA Substance Registry System: Benzene, 1-ethyl-3-(trifluoromethyl)-(27190-70-1)

Safety Data

• Hazardous Substances Data: 27190-70-1(Hazardous Substances Data)

Upstream product

• 402-24-4 3-(trifluoromethyl)styrene 
• 62-53-3 aniline 
• 401-78-5 3-bromo-1-trifluoromethylbenzene 
• 2386-64-3 ethylmagnesium chloride 
• 98-15-7 3-chlorotrifluoromethylbenzene 
• 74-85-1 ethene 
• 98-08-8 α,α,α-trifluorotoluene 
• 100-41-4 ethylbenzene 
• 93683-27-3 perfluoro-2,4-dimethyl-3-ethylpent-3-yl radical 
• 2926-29-6 Langlois reagent 
• 1190235-39-2 4,4,5,5-tetramethyl-2-[[3-(trifluoromethyl)phenyl]methyl]-1,3,2-dioxaborolane 
• 74-88-4 methyl iodide 
• 349-76-8 3'-(trifluoromethyl)acetophenone 
• 437762-10-2 ((S)-1-Phenyl-ethyl)-[(S)-1-(3-trifluoromethyl-phenyl)-ethyl]-amine 

Downstream Products

• 87617-22-9 2-nitro-5-ethylbenzotrifluoride 
• 92891-24-2 2-nitro-3-ethyl benzotrifluoride 

Relevant articles and documents

Selective hydrothermal reductions using geomimicry

Reduction of carbon-carbon π-bonds has been demonstrated using iron powder as the reductant and simple powdered nickel as the catalyst in water as the solvent at 250 °C and the saturated water vapor pressure, 40 bars. Stereochemical, kinetic and electronic probes of the mechanism suggest reaction via a conventional Horiuti-Polyani process for hydrogenation at the nickel metal surface. Selective reduction of carbon-carbon π-bonds is observed in the presence of other functional groups. The reactions use benign and Earth-abundant reagents that are at low depletion risk and take place in water as the only solvent under conditions that are characteristic of many geochemical processes.

Introducing a new radical trifluoromethylation reagent

Perfluoro-3-ethyl-2,4-dimethyl-3-pentyl radical (PPFR) is a persistent radical stable at room temperature, but easily decomposes at 90 °C to produce a CF3 radical which is able to react with a variety of aromatic compounds to afford the corresponding trifluoromethyl derivatives, usually as mixtures of regioisomers in good to excellent overall yields.

Pd0-mediated rapid coupling of methyl iodide with excess amounts of benzyl- and cinnamylboronic acid esters: Efficient method for incorporation of positron-emitting 11C radionuclide into organic frameworks by coupling between two sp<

Pd0-mediated rapid cross coupling between sp3- hybridized carbons of CH3I and benzyl- or cinnamylboronic acid esters using [Pd{P(tert-C4H9)3}2]/CsF in DMF/H2O gave the