272-43-5Relevant articles and documents
In Situ Oxidation Synthesis of p-Type Composite with Narrow-Bandgap Small Organic Molecule Coating on Single-Walled Carbon Nanotube: Flexible Film and Thermoelectric Performance
Gao, Caiyan,Chen, Guangming
, (2018)
Although composites of organic polymers or n-type small molecule/carbon nanotube (CNT) have achieved significant advances in thermoelectric (TE) applications, p-type TE composites of small organic molecules as thick surface coating layers on the surfaces of inorganic nanoparticles still remain a great challenge. Taking advantage of in situ oxidation reaction of thieno[3,4-b]pyrazine (TP) into TP di-N-oxide (TPNO) on single-walled CNT (SWCNT) surface, a novel synthesis strategy is proposed to achieve flexible films of TE composites with narrow-bandgap (1.19 eV) small molecule coating on SWCNT surface. The TE performance can be effectively enhanced and conveniently tuned by poly(sodium-p-styrenesulfonate) content, TPNO/SWCNT mass ratio, and posttreatment by various polar solvents. The maximum of the composite power factor at room temperature is 29.4 ± 1.0 μW m?1 K?2. The work presents a way to achieve flexible films of p-type small organic molecule/inorganic composites with clear surface coating morphology for TE application.
Delay fluorescent compound and using the same and display device having the organic light-emitting diode (by machine translation)
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Paragraph 0324; 0325; 0326; 0327; 0328, (2016/10/08)
The present invention provides a delay fluorescent compound and the use of the compound of the organic light-emitting diode and the display device, the delay fluorescent compound is a type 1 or type 2 delay fluorescent compound : [formula 1] ; [Formula 2] . (by machine translation)
Thieno[3,4-b]pyrazines: Synthesis, structure, and reactivity
Kenning, Don D.,Mitchell, Kari A.,Calhoun, Tessa R.,Funfar, Melanie R.,Sattler, Daniel J.,Rasmussen, Seth C.
, p. 9073 - 9076 (2007/10/03)
A general synthetic route has been developed for the efficient preparation of 2,3-disubstituted thieno[3,4-b]-pyrazines. These methods eliminate problems in the preparation of the precursor 3,4-diaminothiophene and utilize α-diones prepared through the reaction of the appropriate organocuprates with oxalyl chloride. This combination allows the convenient preparation of thieno[3,4-b]pyrazine and its 2,3-disubstituted analogues (where substituent = methyl, hexyl, octyl, decyl, dodecyl, and phenyl) in high yield. Characterization of the structure and reactivity of this class of compounds is also described, including the results of structural, electrochemical, and pKa studies.