2721-25-7Relevant academic research and scientific papers
Orientation in the 1,3-dipolar cycloaddition of diazomethane with alkylethylenes
Firestone, Raymond A.
, p. 2209 - 2212 (1980)
The regiochemistry of diazomethane cycloadditions with simple alkylethylenes, heretofore not reported, was investigated in the simplest case, diazomethane and propene. The products were 3-and 4-methylpyrazolines in 7.4/1 ratio, in accord with the diradical mechanism. This mechanism also accounts for the abnormal orientation in intramolecular cases and with bridgehead olefins.
