272459-41-3Relevant academic research and scientific papers
Titanium-catalyzed Reformatsky-type reaction
Sgreccia, Laura,Bandini, Marco,Morganti, Stefano,Quintavalla, Arianna,Umani-Ronchi, Achille,Cozzi, Pier Giorgio
, p. 3191 - 3197 (2008/02/08)
A catalytic titanium mediated Reformatsky reaction is presented. The technique employs cyclopentadienyltitaniumdichloride(IV) (10 mol%) in conjunction with Mn (2 equiv.), as the stoichiometric reductant, and (CF3CO)2O (1.5 equiv.), a
Electrophilic amination of enolates with oxaziridines: Effects of oxaziridine structure and reaction conditions
Armstrong, Alan,Edmonds, Ian D.,Swarbrick, Martin E.,Treweeke, Nigel R.
, p. 8423 - 8442 (2007/10/03)
A range of N-alkoxycarbonyl- and N-carboxamido-oxaziridines has been prepared to test the effects of oxaziridine structure on yields of enolate amination product. Side-products arising from reaction of aldehyde-derived oxaziridines with base were identified, while a ketone-derived oxaziridine afforded moderate yields of amination product with stabilised carbanions.
Electrophilic amination of carbanions by N-carboxamido oxaziridines
Armstrong, Alan,Atkin, Mark A.,Swallow, Steven
, p. 2247 - 2251 (2007/10/03)
A range of 3-aryl-N-carboxamido oxaziridines have been prepared and tested as reagents for electrophilic amination of carbanions. The 3-(2- cyanophenyl)-derivative gave highest yields of amination product, and was used for amination of ketone, ester and a
