272775-99-2

Upstream product

• 222296-31-3 6-chloro- 9-((2-(trimethylsilyl)ethoxy)methyl)-9H-purine 
• 272775-98-1 Acetic acid (S)-2-((2R,3R,4R,5R,6S)-6-amino-3-azido-4,5-bis-benzyloxy-tetrahydro-pyran-2-yl)-2-benzyloxy-ethyl ester 
• 87-89-8 D-myo-inositol 
• 434300-61-5 1L-1-O-benzoyl-3,6-di-O-benzyl-2-O-methanesulfonyl-4,5-di-O-(p-methoxybenzyl)-myo-inositol 
• 272775-89-0 1L-1-azido-2-O-benzoyl-3,6-di-O-benzyl-1-deoxy-4,5-di-O-(p-methoxybenzyl)-scyllo-inositol 
• 434300-60-4 1L-1-O-bezoyl-3,6-di-O-benzyl-4,5-di-O-(p-methoxybenzyl)-myo-inositol 
• 330801-88-2 1L-1-azido-3,6-di-O-benzyl-1-deoxy-2-O-methanesulfonyl-4,5-di-O-(p-methoxybenzyl)-scyllo-inositol 
• 272775-90-3 1L-2-O-acetyl-1-azido-3,6-di-O-benzyl-1-deoxy-4,5-di-O-(p-methoxybenzyl)-myo-inositol 
• 330801-87-1 1L-1-azido-3,6-di-O-benzyl-1-deoxy-4,5-di-O-(p-methoxybenzyl)-scyllo-inositol 
• 272775-95-8 Acetic acid (2S,3R,4R,5R,6R)-6-((S)-2-acetoxy-1-benzyloxy-ethyl)-5-azido-3,4-bis-benzyloxy-tetrahydro-pyran-2-yl ester 
• 272775-97-0 Acetic acid (S)-2-benzyloxy-2-((2R,3R,4R,5R,6S)-3,6-diazido-4,5-bis-benzyloxy-tetrahydro-pyran-2-yl)-ethyl ester 
• 272775-96-9 Acetic acid (S)-2-((2R,3R,4R,5R,6S)-3-azido-4,5-bis-benzyloxy-6-bromo-tetrahydro-pyran-2-yl)-2-benzyloxy-ethyl ester 
• 272775-94-7 (3S,4R,5R,6R,7S)-5-azido-3,4,7-tribenzyloxy-6,8-isopropylidenedioxyoct-1-en 
• 434300-64-8 (2R,3R,4R)-4-Azido-2,3-bis-benzyloxy-4-((4R,5S)-5-benzyloxy-2,2-dimethyl-[1,3]dioxan-4-yl)-butyraldehyde 

Relevant academic research and scientific papers

Total synthesis of spicamycin amino nucleoside.

[formula: see text] The first total synthesis of spicamycin amino nucleoside 2 has been achieved. The aminoheptose unit 5 was prepared stereoselectively from myo-inositol, and the characteristic N-glycoside linkage was constructed by way of Pd-catalyzed coupling reaction of 5 with 6-chloropurine derivative 6.