272788-38-2Relevant academic research and scientific papers
New preparation of difluoroiodomethylsulfanylbenzenes and their radical addition to unsaturated compounds initiated by sodium dithionite
Yang, Xueyan,Fang, Xiang,Yang, Xianjin,Zhao, Min,Han, Yizheng,Shen, Yongjia,Wu, Fanhong
, p. 2259 - 2269 (2008/09/18)
Difluoroiodomethylsulfanylbenzene (3a) and 1-chloro-4-difluoroiodomethylsulfanylbenzene (3b) are novel and efficient difluoromethylating reagents via the reaction with unsaturated compounds, such as alkenes, ethynylbenzene, pent-4-en-1-ols, and pent-4-eno
AIBN-initiated radical addition of gem-difluorinated alkyl iodides to alkynes and the Pd-catalyzed Sonogashira coupling reaction of E-phenyl difluoromethylene vinylic iodides with terminal alkynes
Fang, Xiang,Yang, Xueyan,Yang, Xianjin,Mao, Shenjie,Wang, Zhonghua,Chen, Guorong,Wu, Fanhong
, p. 10684 - 10692 (2008/02/13)
The addition of gem-difluorinated alkyl iodides to alkynes initiated by AIBN neatly gave the corresponding difluoromethylene vinyl iodides among which the stereoselectivity of aromatic acetylenes was high. The further coupling reaction of E-phenyl difluor
Aryliododifluoromethylsulfides, sulfoxides and sulfones: The first optically active compounds with polyfluoroalkyliodo groups
Yagupolskii, Lev M.,Matsnev, Andrej V.
, p. 132 - 134 (2007/10/03)
Aryliododifluoromethyl sulfoxides, which were transformed in aryliododifluoromethyl sulfides and sulfones, were obtained by the coupling of mercury salts of arylsulfoxydifluoromethylacetic acids with iodine.
The reactions of difluorodiiodomethane with nucleophiles
Guo, Yong,Chen, Qing-Yun
, p. 105 - 109 (2007/10/03)
Treatment of difluorodiiodomethane with phenoxides (ArO-) in DMF at room temperature gives ArOCF2I in 7-15%, the carbonates (ArOCO2Ar) being the major products, while with thiophenoxides affords difluoromethylene derivativ
