273196-08-0Relevant academic research and scientific papers
Study on the structureeproperty relationship in a series of novel BF2 chelates with multicolor fluorescence
Yao, Qi-Chao,Wu, Ding-Er,Ma, Ru-Zheng,Xia, Min
, p. 1 - 9 (2013/10/08)
A series of multicolor fluorescent N,O-bidentate BF2 complexes with variable ligand structures have been synthesized. These complexes exhibit the solvent-independent optical properties and large Stoke shifts. The electrochemical measurements demonstrate that all these chelates are better electron acceptors than the commonly used material Alq3. A qualitative structureeproperty relationship among these complexes has been established on the ground of the experimental data along with the density functional theory (DFT) calculations. The theoretically calculated results are in good agreement with those obtained by the experimental determinations.
