27371-67-1Relevant academic research and scientific papers
Ligand Rearrangement Leads to Tetrahydrothiophene-Functionalized N,S-Heterocyclic Carbene Palladium(II) Complexes
Romine, Andrew M.,Demer, Matthew J.,Gembicky, Milan,Rheingold, Arnold L.,Engle, Keary M.
, p. 2311 - 2319 (2021)
Tetrahydrothiophene-functionalized N,S-heterocyclic carbene palladium(II) complexes are synthesized through an unexpected rearrangement that proceeds with palladium(II) trifluoroacetate but not with palladium(II) acetate, palladium(II) bromide, or palladium(II) chloride. A series of these complexes were isolated and characterized by X-ray crystallography. The mechanism of formation of these [3.2.1]palladabicycles was explored, and the catalytic capabilities of these complexes were demonstrated in representative C-C coupling reactions.
