274679-39-9

Basic information

• Product Name: p-tolyl 2-diazoacetate
• Synonyms: p-tolyl 2-diazoacetate
• CAS NO: 274679-39-9
• Molecular Weight: 176.175
• Mol File: 274679-39-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: p-tolyl 2-diazoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: p-tolyl 2-diazoacetate(274679-39-9)
• EPA Substance Registry System: p-tolyl 2-diazoacetate(274679-39-9)

Safety Data

• Hazardous Substances Data: 274679-39-9(Hazardous Substances Data)

Upstream product

• 106-44-5 p-cresol 
• 38829-10-6 Bromessigsaeure-(p-tolyl)ester 
• 186581-53-3 diazomethane 
• 937-62-2 p-tolyl chloroformate 

Downstream Products

• 15150-39-7 2-chloroacetic acid 4-methylphenyl ester 

Relevant articles and documents

Low-Temperature Intramolecular [4+2] Cycloaddition of Allenes with Arenes for the Synthesis of Diene Ligands

The intramolecular [4+2] cycloaddition between arenes and allenes first reported by Himbert gives rapid access to rigid polycyclic scaffolds. Herein, we report a one-pot oxyalkynylation/cycloaddition reaction proceeding under mild conditions (23–90 °C) an

Chemistry of diazopolycarbonyl compounds: V. Synthesis, structure, and chemical characteristics of aryl diazoacetates

Aryl diazoacetates were prepared, and basing on spectral data and quantum-chemical calculations cis-trans isomerism thereof was proved. The reactions of diazoesters with hydrochloric and sulfuric acids, triphenylphosphine, and dinitrogen tetroxide resulted respectively in aryl chloroacetates, bis(aryloxy-carbonylmethyl) sulfates, triphenylphosphoranylidenehydrazones of aryl 2-oxoethanoates, and N-oxides of diaryl 1,2,5-oxadiazole-3,4-dicarboxylates.