274693-87-7

Basic information

• Product Name: (E)-(S)-1-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-5-methyl-hept-5-en-3-ol
• Synonyms: (E)-(S)-1-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-5-methyl-hept-5-en-3-ol
• CAS NO: 274693-87-7
• Molecular Weight: 364.601
• Mol File: 274693-87-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(S)-1-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-5-methyl-hept-5-en-3-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(S)-1-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-5-methyl-hept-5-en-3-ol(274693-87-7)
• EPA Substance Registry System: (E)-(S)-1-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-5-methyl-hept-5-en-3-ol(274693-87-7)

Safety Data

• Hazardous Substances Data: 274693-87-7(Hazardous Substances Data)

Upstream product

• 115114-87-9 (2R)-2-(2-benzyloxyethyl)oxirane 
• 143236-64-0 (E)-2-bromo-4-(tert-butyldimethylsilyloxy)-2-butene 

Downstream Products

• 274693-95-7 (E)-(2S,4R,9R,11R,12S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxy)-4,11,12-trimethyl-9-triisopropylsilanyloxy-tridec-5-en-7-ol 
• 274693-96-8 (E)-(2S,4R,9S,11R,12S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxy)-4,11,12-trimethyl-9-triisopropylsilanyloxy-tridec-5-en-7-one 
• 274693-93-5 [(3R,5R,6S)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethyl-3-triisopropylsilanyloxy-heptyloxymethyl]-benzene 
• 274693-92-4 (2S,3R,5R)-7-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-2,3-dimethyl-5-triisopropylsilanyloxy-heptan-3-ol 
• 274693-91-3 (2R,3R)-2-((R)-4-Benzyloxy-2-triisopropylsilanyloxy-butyl)-3-(tert-butyl-dimethyl-silanyloxymethyl)-2-methyl-oxirane 
• 274693-90-2 [(2R,3R)-3-((R)-4-Benzyloxy-2-triisopropylsilanyloxy-butyl)-3-methyl-oxiranyl]-methanol 
• 274693-89-9 (E)-(S)-7-Benzyloxy-3-methyl-5-triisopropylsilanyloxy-hept-2-en-1-ol 
• 274693-88-8 [(E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-5-methyl-3-triisopropylsilanyloxy-hept-5-enyloxymethyl]-benzene 

Relevant articles and documents

Enantioselective synthesis of the C14-C25 portion of the cytotoxic natural product, amphidinolide B1

The C14-C25 portion of the cytotoxic natural product, amphidinolide B1 (1), was synthesized enantioselectively using Myers asymmetric alkylation protocol, epoxide opening with higher order cuprate, Sharpless asymmetric epoxidation of allylic alcohol 17, a