274693-91-3

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 274693-90-2 [(2R,3R)-3-((R)-4-Benzyloxy-2-triisopropylsilanyloxy-butyl)-3-methyl-oxiranyl]-methanol 
• 274693-87-7 (E)-(S)-1-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxy)-5-methyl-hept-5-en-3-ol 
• 274693-89-9 (E)-(S)-7-Benzyloxy-3-methyl-5-triisopropylsilanyloxy-hept-2-en-1-ol 
• 274693-88-8 [(E)-(S)-7-(tert-Butyl-dimethyl-silanyloxy)-5-methyl-3-triisopropylsilanyloxy-hept-5-enyloxymethyl]-benzene 

Downstream Products

• 274693-92-4 (2S,3R,5R)-7-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-2,3-dimethyl-5-triisopropylsilanyloxy-heptan-3-ol 
• 274693-93-5 [(3R,5R,6S)-5,7-Bis-(tert-butyl-dimethyl-silanyloxy)-5,6-dimethyl-3-triisopropylsilanyloxy-heptyloxymethyl]-benzene 
• 274693-96-8 (E)-(2S,4R,9S,11R,12S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxy)-4,11,12-trimethyl-9-triisopropylsilanyloxy-tridec-5-en-7-one 
• 274693-95-7 (E)-(2S,4R,9R,11R,12S)-11,13-Bis-(tert-butyl-dimethyl-silanyloxy)-2-(4-methoxy-benzyloxy)-4,11,12-trimethyl-9-triisopropylsilanyloxy-tridec-5-en-7-ol 

Relevant academic research and scientific papers

Enantioselective synthesis of the C14-C25 portion of the cytotoxic natural product, amphidinolide B1

The C14-C25 portion of the cytotoxic natural product, amphidinolide B1 (1), was synthesized enantioselectively using Myers asymmetric alkylation protocol, epoxide opening with higher order cuprate, Sharpless asymmetric epoxidation of allylic alcohol 17, a