2747-48-0Relevant articles and documents
Effect of the metal catalyst on the mechanism of hydrogenation of C6 acetylenic carbinols
Sokolo'skii, D. V.,Zhubanova, L. K.,Omarkulov, T. O.,Sadykov, U. A.,Korolev, A. V.
, p. 43 - 46 (2007/10/02)
The most probable mechanism of the hydrogenation of tertiary and of primary C6 acetylenic carbinols on group VIII metals are discussed.By using mathematical modelling and deuterium exchange methods we have shown that in the presence of Pd, Rh, and Pt the reaction takes place by a series mechanism, whereas on Ru black the acetylenic C6 alcohols are hydrogenated by a series-parallel scheme.