27470-41-3

Basic information

• Product Name: Hydroperoxide, (4-methylcyclohexylidene)bis-
• CAS NO: 27470-41-3
• Molecular Formula: C7H14O4
• Molecular Weight: 162.186
• Mol File: 27470-41-3.mol
• Article Data: 18

Chemical Properties

• CAS DataBase Reference: Hydroperoxide, (4-methylcyclohexylidene)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Hydroperoxide, (4-methylcyclohexylidene)bis-(27470-41-3)
• EPA Substance Registry System: Hydroperoxide, (4-methylcyclohexylidene)bis-(27470-41-3)

Safety Data

• Hazardous Substances Data: 27470-41-3(Hazardous Substances Data)

Upstream product

• 18349-20-7 4-methylcyclohexanone dimethyl acetal 
• 589-92-4 1-methylcyclohexan-4-one 

Downstream Products

• 54121-55-0 1-(2-chlorophenyl)piperidine 
• 1097634-89-3 1-hydroperoxy-1-(2-methoxypropan-2-ylperoxy)-4-methylcyclohexane 
• 1097634-93-9 1-(1-hydroperoxy-4-methylcyclohexylperoxy)-1-methoxycycloheptane 
• 1097634-91-7 1-(1-ethoxycyclopentylperoxy)-1-hydroperoxy-4-methylcyclohexane 
• 1097634-92-8 1-hydroperoxy-1-(1-methoxycyclohexylperoxy)-4-methylcyclohexane 
• 1097634-90-6 1-hydroperoxy-1-(2-methoxynonan-2-ylperoxy)-4-methylcyclohexane 
• 1101829-27-9 C₁₉H₄₂O₄Si₂ 

Relevant articles and documents

Kinetics of the electrochemical oxidation of 1,1-bis-hydroperoxy-4- methylcyclohexane on platinum

The electrochemical synthesis of 3,12-dimethyl-7,8,15,16-tetraoxadispiro[5. 2.5.2]hexadecane (1,2,4,5-tetraoxane) from 1,1-bis-hydroperoxy-4- methylcyclohexane on platinum electrode in a cell with separated and unseparated cathode and anode space in an aprotic solvent is conducted. The kinetics of electrochemical oxidation of 1,1-bis(hydroperoxy)-4-methylcyclohexane is studied. The current yield of the reaction is determined.

Sulfamic acid: as a green and reusable homogeneous catalyst for peroxidation of ketones and aldehydes using aqueous 30 % H2O2

Abstract Sulfamic acid has been used as an active, low-cost and reusable solid catalyst for conversion of ketones and aldehydes to corresponding gem-dihydroperoxides using 30 % aqueous hydrogen peroxide at room temperature. The reactions proceed with high rates and excellent yields.

Poly(N-vinylpyrrolidone)-H2O2 and poly(4-vinylpyridine)-H2O2 complexes: Solid H 2O2 equivalents for selective oxidation of sulfides to sulfoxides and ketones to gem-dihydroperoxides

Complexes of poly(N-vinylpyrrolidone) (PVD) and poly(4-vinylpyridine) (PVP) with hydrogen peroxide have been prepared and their synthetic utility as solid H2O2 equivalents for the selective oxidation of sulfides to sulfoxides and ketones to gem-dihydroperoxides has been studied. These complexes are convenient and safe alternatives to H2O2 solutions and it is found that various symmetric as well as unsymmetrical sulfides undergo oxidation under mild conditions to provide the respective sulfoxides in high yields. A series of gem-dihydroperoxides were obtained from the corresponding ketones in good yields under ambient conditions. This journal is the Partner Organisations 2014.