27484-20-4Relevant articles and documents
Dehydropolymerization of arylsilanes catalyzed by a novel silylmolybdenum complex
Minato, Makoto,Matsumoto, Takaomi,Ichikawa, Miyuki,Ito, Takashi
, p. 2968 - 2969 (2003)
A complex [MoH3[Si(Ph)[Ph2PCH2CH 2P(Ph)C6H4-o]2]] (1) can act as single-component catalyst for dehydrogenative polymerization of ArSiH 2R (Ar = Ph, p-tolyl, o-tolyl; R = H, Me) to (ArSiR)n: p- and o- tolylsilane produced the polymers of respectable molecular weights (MW of 17300 and 6700 respectively) and polymerization of secondary silane, methylphenylsilane, gave a substantial molecular weight (MW of 1750).
Reactivity of group 4 benzamidinate complexes towards mono- and bis-substituted silanes and 1,5-hexadiene
Volkis, Victoria,Averbuj, Claudia,Eisen, Moris S.
, p. 1940 - 1950 (2007/10/03)
Zirconium and titanium bis(benzamidinate) dimethyl complexes were found to be active catalytic precursors for the oligomerization of mono- and bis-substituted silanes. The activation of such complexes, by an excess of MAO or by an equimolar amount of B(C
Rapid, highly linear-selective dehydrocoupling of phenylsilane with new group 4 metallocene-based combination catalysts
Woo, Hee-Gweon,Song, Sun-Jung
, p. 457 - 458 (2007/10/03)
The dehydrocoupling of phenylsilane with Cp12MCl2/Red-Al (Cp1 = C5H5 or C5Me5; M = Ti, Zr, Hf; Red-Al = Na[H2Al(OCH2CH2OMe)2/sub