27490-31-9

Basic information

• Product Name: (tri(n-butyl)stannyl)dimethylsilane
• Synonyms: (tri(n-butyl)stannyl)dimethylsilane
• CAS NO: 27490-31-9
• Molecular Weight: 349.219
• Mol File: 27490-31-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (tri(n-butyl)stannyl)dimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (tri(n-butyl)stannyl)dimethylsilane(27490-31-9)
• EPA Substance Registry System: (tri(n-butyl)stannyl)dimethylsilane(27490-31-9)

Safety Data

• Hazardous Substances Data: 27490-31-9(Hazardous Substances Data)

Upstream product

• 688-73-3 tri-n-butyl-tin hydride 
• 86840-61-1 13,13-Dimethyl-1,10-diphenyl-13-silatricyclo<8.2.1.0^Δ2,9>trideca-11-en 

Downstream Products

• 55227-55-9 1,1-dimethyl-3,4-diphenylsilole 
• 66680-87-3 (E)-1-phenyl-(2-tributylstannyl)ethene 
• 813-19-4 bis(tri-n-butyltin) 
• 92074-28-7 1-phenyl-1-(tributylstannyl)ethene 

Relevant articles and documents

DIE CHEMIE DER SCHWEREN CARBEN-ANALOGEN R2M, M=Si, Ge, Sn. X. 7-SILA-NORBORNADIENE: REAKTIONEN MIT HALOGENEN UND THERMOLYSE IN GEGENWART VON METALLORGANISCHEN ODER ORGANISCHEN HALOGENIDEN

The 7-sila-norbornadienes (I-IV) react rapidly with halogens at -20 to +20 deg C to yield Me2SiHal2 (Hal=Cl, Br, I) and the naphthalene or benzene derivatives (V-VIII).Bromine in CCl4 at 0 deg C, however, caused surprising rearrangement in I giving the 2-bromosilylated naphthalene (IX), since an attack at the alkene group seemed to be preferred.Methylation and methoxylation of IX gave respectively X and XI.Careful hydrolysis of IX yielded the disiloxane XII.Insertions of Me2Si into the Si-Hal, Si-H, Si-C, or Sn-C bonds were not observed at 160-200 deg C, whereas insertions into Sn-Cl or Sn-H bonds occurred smoothly via a one-step mechanism.Halogen is abstracted from different C-Hal bonds leading to Me2SiHal2 and sometimes to Me4Si2Hal2.The degradation of the silylene precursors in these cases is always first order and resembles that of spontaneous thermolysis.