27530-75-2Relevant articles and documents
A convenient preparative method of dibromoterphenyl and Bis(bromophenyl)diene monomers using zirconacyclopentadienes
Takahashi, Tamotsu,Tsai, Fu-Yu,Yanzhong, Li
, p. 1173 - 1174 (2007/10/03)
Zirconacyclopentadienes prepared from 4,4′-dibromodiphenyldiynes or 1-(4′-bromophenyl)-1-alkynes reacted with dimethylacetylene dicarboxylate in the presence of CuCl afforded polyphenylene monomers which contain three benzene rings. Hydrolysis, chlorination with NCS, or allylation of the zirconacyclopentadienes gave a variety of polyphenylenedienylene monomers. Polymerization of these monomers using the system NiCl2(PPh3)2 (cat.)/Zn produced the corresponding polymers.