275369-88-5

Basic information

• Product Name: [(C₆F₅)2Pd(C₃H₃N₂)2Pd(P(C₂H₅)3)2]
• CAS NO: 275369-88-5
• Molecular Weight: 917.414
• Mol File: 275369-88-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(C₆F₅)2Pd(C₃H₃N₂)2Pd(P(C₂H₅)3)2](CAS DataBase Reference)
• NIST Chemistry Reference: [(C₆F₅)2Pd(C₃H₃N₂)2Pd(P(C₂H₅)3)2](275369-88-5)
• EPA Substance Registry System: [(C₆F₅)2Pd(C₃H₃N₂)2Pd(P(C₂H₅)3)2](275369-88-5)

Safety Data

• Hazardous Substances Data: 275369-88-5(Hazardous Substances Data)

Upstream product

• 28425-04-9 dichlorobis(triethylphosphine)palladium(II) 
• 143886-99-1 (C₄H₉)4N⁽¹⁺⁾*(C₆F₅)2Pd(C₃N₂H₄)(C₃N₂H₃)^(1-)=(C₄H₉)4N(C₆F₅)2Pd(C₃N₂H₄)(C₃N₂H₃) 

Relevant articles and documents

New di- and trinuclear complexes with pyrazolato bridges. Crystal structures of [{(C6F5)2Pd(μ-pz)(μ-Cl)}2Pd]2- and [(C6F5)2Pd(μ- pz)2Pd(η3-C4H7)] (pz = pyrazolate)

Trinuclear complexes containing pyrazolate bridging ligands of the type [NBu4]2[{(C6F5)2 M(μ-pz)(μ-X)}2M'] (M, M' = Pd or Pt; X = Cl, OH, or pz) (Hpz = pyrazole) have been prepared using [NBu4][M(C6F5)2(acac)] (acac = acetylacetonate) or [NBu4]2[M2(C6F5)4(μ-OH)2] and [M'Cl2(Hpz)2] or [M'(Hpz)4]2+ as starting materials. Asymmetric homo- and heterobimetallic complexes of the types [NBu4][R2M(μpz)2Pd(η3- allyl)] and [R2M(μ-pz)2M'L2] (allyl = C3H5 or C4H?; L2 = 2 PEt3 or bipy; R = C6F5 or C6Cl5; M, M' = Pd or Pt) have been obtained starting from [NBu4][MR2(pzHpz)] and [Pd(η3allyl)(acac)] or [M'L2Cl2], respectively. The identity of the new complexes has been established by NMR (1H, 19F and 31P) spectroscopy. The crystal structure of [{(C6F5)2Pd(μ- pz)(μ-C1)}2Pd]2- has an inversion centre, with a bent appearance of the Pd3(μ-pz)2(μ-Cl)2 moiety. The crystal structure of [(C6F5)2Pd(μ-pz)2Pd(η3-C4Hy)] has also been determined by single- crystal X-ray diffraction, where a boat conformation of the central 'Pd2N4' six-membered rings is observed.