275377-30-5Relevant articles and documents
Synthesis of 2,2-difluoro-homoallylic alcohols via ring-opening of gem-difluorocyclopropane and aerobic oxidation by photo-irradiation in the presence of an organic pigment
Takenaka, Hiroaki,Masuhara, Yoshihiro,Narita, Kent,Nokami, Toshiki,Itoh, Toshiyuki
, p. 6106 - 6114 (2018/09/06)
We found that aerobic oxidation took place after the visible light-mediated ring-opening reaction of gem-difluorocyclopropane in the presence of an organic dye and amine to furnish 2,2-difluoro-homoallylic alcohols in good yields.
Synthesis of 4,4-difluoroglycosides using ring-closing metathesis
Audouard, Christophe,Fawcett, John,Griffiths, Gerry A.,Percy, Jonathan M.,Pintat, Stephane,Smith, Clive A.
, p. 528 - 541 (2007/10/03)
4-Deoxy-4,4-difluoro-glycosides have been synthesised for the first time via a direct sequence involving ring-closing metathesis and indium-mediated difluoroallylation with 1-bromo-1,1-difluoropropene in water. Two protecting group strategies were explore
