27549-72-0Relevant articles and documents
Reductive coupling of aromatic aldehydes and imines by the low valent titanium species generated in the reaction of TiCl4 with Et3N
Periasamy, Mariappan,Srinivas, Gadthula,Karunakar, Galla V.,Bharathi, Pandi
, p. 7577 - 7580 (1999)
Aromatic aldehydes and imines are converted to the corresponding diols and diamines using the low valent titanium species generated by the reaction of TiCl4 with triethylamine.
Direct reductive coupling of secondary amides: Chemoselective formation of vicinal diamines and vicinal amino alcohols
Huang, Pei-Qiang,Lang, Qi-Wei,Wang, Ai-E,Zheng, Jian-Feng
supporting information, p. 1096 - 1099 (2015/02/19)
We report the first one-pot reductive homocoupling reaction of secondary amides and cross-coupling reaction of secondary amides with ketones to give secondary vicinal diamines and amino alcohols. This method relies on the direct generation of α-amino carb
Zn-mediated catalytic photoreduction of aldimines. One-pot synthesis and separation of meso and d,l C2 symmetrical diamines
Ortega, María,Rodríguez, Miguel A.,Campos, Pedro J.
, p. 6475 - 6478 (2007/10/03)
A new one-pot method for the synthesis and selective separation of 1,2-diamines is reported. The methodology, which involves the photoreduction of imines using catalytic amounts of zinc as a photosensitizer, allows the direct preparation and separation of meso and d,l compounds on a multigram scale.