27570-06-5

Basic information

• Product Name: Benzyl alcohol, .alpha.-(1-bromoethyl)-, formate, threo-
• Synonyms: Benzyl alcohol, .alpha.-(1-bromoethyl)-, formate, threo-
• CAS NO: 27570-06-5
• Molecular Formula: C₁₀H₁₁BrO₂
• Molecular Weight: 243.1
• Mol File: 27570-06-5.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 270.8±28.0 °C(Predicted)
• Appearance: /
• Density: 1.403±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzyl alcohol, .alpha.-(1-bromoethyl)-, formate, threo-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyl alcohol, .alpha.-(1-bromoethyl)-, formate, threo-(27570-06-5)
• EPA Substance Registry System: Benzyl alcohol, .alpha.-(1-bromoethyl)-, formate, threo-(27570-06-5)

Safety Data

• Hazardous Substances Data: 27570-06-5(Hazardous Substances Data)

Upstream product

• 873-66-5 1-propenylbenzene 
• 68-12-2 N,N-dimethyl-formamide 
• 64-18-6 formic acid 

Relevant articles and documents

A simple and facile method for regio- and stereoselective bromoformyloxylation and bromoacetoxylation of olefins using NH4Br and oxone

A mild and efficient protocol for the preparation of bromoformates as well as bromoacetates from olefins using NH4Br and oxone in nucleophile sources (DMF or DMA) without employing catalyst at room temperature is described. This method is facile, environmentally friendly and cost effective. A variety of terminal, internal and cyclic alkenes reacted smoothly to give the corresponding bromoformate and acetate products in good to excellent yields. Moreover, 1,2-disubstituted olefins provided moderate to excellent diastereoselectivity.