27573-55-3Relevant academic research and scientific papers
Denitrogenative Suzuki and carbonylative Suzuki coupling reactions of benzotriazoles with boronic acids
Wang, Yuanhao,Wu, Yunfei,Li, Yuanhe,Tang, Yefeng
, p. 3852 - 3857 (2017)
Unprecedented palladium-catalyzed denitrogenative Suzuki and carbonylative Suzuki coupling reactions of benzotriazoles with boronic acids have been realized, which afforded structurally diverse ortho-amino-substituted biaryl and biaryl ketone derivatives. The key to this success is due to the development of a rationally designed strategy to achieve the ring opening of benzotriazoles with a synergistic activating-stabilizing effect, which enables the in situ generation of the corresponding ortho-amino-arenediazonium species. The present work opens up a new avenue to utilize benzotriazoles as synthetic equivalents of ortho-amino-arenediazoniums, which otherwise could not be directly accessed by existing synthetic methods.
Control of parasites in animals by the use of novel trifluoromethanesulfonanilide oxime ether derivatives
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Page/Page column 31; 7/12, (2010/10/20)
Novel trifluoromethanesulfonanilide oxime ether compounds useful for controlling endo and/or ectoparasites in the environment are provided, together with methods of making the same, and methods of using the inventive compounds to treat parasite infestations in vivo or ex vivo.
