27591-56-6Relevant academic research and scientific papers
THE FRAGMENTATION OF BENZYLOXYCHLOROCARBENE: FORMATION OF BENZYL CATION
Moss, Robert A.,Wilk, Bogdan K.,Hadel, Linda M.
, p. 1969 - 1972 (1987)
Thermolysis of 3-benzyloxy-3-chlorodiazirine in MeCN at 25 deg C affords benzyloxychlorocarbene that fragments cleanly to the benzyl cation.
Anomalous One-pot Transformation of 3-Dimethoxymethyl-2-(N-cyanoimino)thiazolidine into 6-Unsubstituted 2,4-Diamino-s-triazines by the Reaction with Amines
Tanaka, Tetsuaki,Watanabe, Mayumi,Nakamoto, Yumi,Okuno, Kaori,Maekawa, Kaori,Iwata, Chuzo
, p. 2301 - 2302 (2007/10/02)
3-Dimethoxymethyl-2-(N-cyanoimino)thiazolidine 1e reacts with secondary amines to afford 2,4-diamino-s-triazines 4 unexpectedly, while the triazine 5 bearing different amino groups at 2 and 4 positions is selectively obtained by the reaction with a mixture of two kinds of amines.
