276856-74-7

Basic information

• Product Name: methyl (Z)-3-(3,5)-xylyl-2-butenoate
• Synonyms: methyl (Z)-3-(3,5)-xylyl-2-butenoate
• CAS NO: 276856-74-7
• Molecular Weight: 204.269
• Mol File: 276856-74-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl (Z)-3-(3,5)-xylyl-2-butenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (Z)-3-(3,5)-xylyl-2-butenoate(276856-74-7)
• EPA Substance Registry System: methyl (Z)-3-(3,5)-xylyl-2-butenoate(276856-74-7)

Safety Data

• Hazardous Substances Data: 276856-74-7(Hazardous Substances Data)

Upstream product

• 5379-16-8 3,5-dimethylacetophenone 
• 88738-78-7 bis-(2,2,2-trifluoroethyl)(methoxycarbonylmethyl)phosphonate 

Relevant articles and documents

A facile method for the stereoselective Horner-Wadsworth-Emmons reaction of aryl alkyl ketones.

Excellent Z or E selectivity was observed in the Horner-Wadsworth-Emmons (HWE) reactions of methyl bis(2,2,2-trifluoroethyl)phosphonoacetate or ethyl 2-fluoro-2-diethylphosphonoacetate with aryl alkyl ketones bearing substituents on an aromatic moiety employing Sn(OSO2CF3)2 in the presence of N-ethylpiperidine.