27732-42-9Relevant academic research and scientific papers
Oxidative Dehydrogenation on Nanocarbon: Revealing the Reaction Mechanism via In Situ Experimental Strategies
Wang, Chao,Liu, Wei,Wei, Shimeng,Su, Dangsheng,Qi, Wei
, p. 397 - 400 (2018/11/23)
Classical mechanistic analysis strategy, including active site chemical titration, kinetic measurement and corresponding isotopic effect and surface reaction of single reactant etc., were performed in oxidative dehydrogenation reactions on nanocarbon. The
Nanocarbon as robust catalyst: Mechanistic insight into carbon-mediated catalysis
Zhang, Jian,Su, Dangsheng,Zhang, Aihua,Wang, Di,Schloegl, Robert,Hebert, Cecile
, p. 7319 - 7323 (2008/09/18)
(Figure Presented) Kicking the coke habit: In nanocarbon-catalyzed oxidative dehydrogenation of ethylbenzene, oxygen is dissociatively adsorbed, and breaking of C-H bonds in ethylbenzene is kinetically relevant. In contrast to metal-based catalysts, the subsurface structure plays no role in the activity of the nanocarbon catalyst. Unlike activated carbon, the nanocarbon catalysts show no loss of activity from coking or combustion.
PREPARATION OF DEUTERIATED 1-PHENYLETHANOLS BY REDUCTIVE DEHALOGENATION OF THE CORRESPONDING HALOGENOACETOPHENONES WITH RANEY ALLOYS IN AN ALKALINE DEUTERIUM OXIDE SOLUTION
Tashiro, Masashi,Mataka, Shuntaro,Nakamura, Hiroshi,Nakayama, Kouji
, p. 179 - 182 (2007/10/02)
Deuteriated 1-phenylethanols were prepared by reductive dehalogenation of the corresponding halogenoacetophenones with Raney Ni-Al and Cu-Al alloys in 5percent NaOD-D2O solution.It was found that the Ni-Al alloy introduced greater than expected numbers of deuterium atoms in the phenyl ring, but the expected deuteriated 1-phenylethanols were obtained in high yield and in high isotopic purity when Raney Cu-Al alloy was used.
