2779-29-5Relevant academic research and scientific papers
Copper-catalyzed formic acid synthesis from CO2 with hydrosilanes and H2O
Motokura, Ken,Kashiwame, Daiki,Miyaji, Akimitsu,Baba, Toshihide
, p. 2642 - 2645 (2012)
A copper-catalyzed formic acid synthesis from CO2 with hydrosilanes has been accomplished. The Cu(OAc)2?H 2O-1,2-bis(diphenylphosphino)benzene system is highly effective for the formic acid synthesis under 1 atm of CO2. The TON value approached 8100 in 6 h. The reaction pathway was revealed by in situ NMR analysis and isotopic experiments.
Bio-inspired oxidation of methane in water catalyzed by N-bridged diiron phthalocyanine complex
Sorokin, Alexander B.,Kudrik, Evgeny V.,Bouchu, Denis
supporting information; body text, p. 2562 - 2564 (2009/02/04)
A stable μ-nitrido diiron phthalocyanine activates H2O 2 to oxidize CH4 in water at 25-60 °C to methanol, formaldehyde and formic acid as evidenced using 13C and 18O labelling. The Royal Society of Chemistry.
