27854-93-9Relevant articles and documents
Stereospecific Intramolecular Arylation of 2- and 3-Pyridyl Substituted Alkylamines via Configurationally Stable α-Pyridyl Organolithiums
Maury, Julien,Zawodny, Wojciech,Clayden, Jonathan
, p. 472 - 475 (2017/02/10)
Treatment of N′-aryl urea derivatives of enantiomerically enriched α-(2-pyridyl) and α-(3-pyridyl)alkylamines with a base leads to the migration of the N′-aryl substituent from N to C in a nonclassical' intramolecular nucleophilic aromatic substitution re
Asymmetric Biocatalytic Amination of Ketones at the Expense of NH3 and Molecular Hydrogen
Holzer, Anja K.,Hiebler, Katharina,Mutti, Francesco G.,Simon, Robert C.,Lauterbach, Lars,Lenz, Oliver,Kroutil, Wolfgang
supporting information, p. 2431 - 2433 (2015/06/02)
A biocatalytic system is presented for the stereoselective amination of ketones at the expense of NH3 and molecular hydrogen. By using a NAD+-reducing hydrogenase, an alanine dehydrogenase, and a suitable ω-transaminase, the R- as well as the S-enantiomer of various amines could be prepared with up to >99% ee and 98% conversion. (Chemical Equation Presented).
Catalytic enantioselective borane reduction of benzyl oximes: Preparation of (S)-1-pyridin-3-YL-ethylamine bis hydrochloride
Huang, Kun,Ortiz-Marciales, Margarita,Hughes, David
experimental part, p. 36 - 52 (2011/05/13)
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