278605-81-5

Basic information

• Product Name: 2H-1,2-Oxazine-4-ethanol, 2-acetyl-3,6-dihydro- (9CI)
• Synonyms: 2H-1,2-Oxazine-4-ethanol, 2-acetyl-3,6-dihydro- (9CI)
• CAS NO: 278605-81-5
• Molecular Formula: C8H13NO3
• Molecular Weight: 171.19372
• Product Categories: ACETYLGROUP
• Mol File: 278605-81-5.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2H-1,2-Oxazine-4-ethanol, 2-acetyl-3,6-dihydro- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-1,2-Oxazine-4-ethanol, 2-acetyl-3,6-dihydro- (9CI)(278605-81-5)
• EPA Substance Registry System: 2H-1,2-Oxazine-4-ethanol, 2-acetyl-3,6-dihydro- (9CI)(278605-81-5)

Safety Data

• Hazardous Substances Data: 278605-81-5(Hazardous Substances Data)

Upstream product

• 546-88-3 acetylhydroxamic acid 
• 27974-99-8 3-methylenepent-4-en-1-ol 
• 278605-84-8 (S)-3,9-Dioxa-1-aza-bicyclo[4.3.1]dec-6-en-2-one 
• 278605-83-7 3-methylene-4-pentenyl N-hydroxycarbamate 
• 75-36-5 acetyl chloride 
• 278605-85-9 4-(2-hydroxyethyl)-3,6-dihydro-2H-[1,2]oxazinee 
• 278605-87-1 4-(2-hydroxyethyl)-3,6-dihydro-2H-[1,2]oxazine-2-carboxylic acid ethyl ester 
• 278605-84-8 3,9-dioxa-1-azabicyclo[4.3.1]dec-6-en-2-one 

Relevant articles and documents

Type 2 intramolecular nitroso Diels-Alder reaction. Synthesis and structure of bridgehead oxazinolactams.

[reaction--see text] The type 2 intramolecular Diels-Alder cycloaddition utilizing N-acylnitroso dienophiles provides an efficient entry into bridged oxazinolactams. In contrast to the bimolecular counterpart, the reaction is completely regioselective. Structural characterization of the cycloadducts allows for evaluation of the olefin distortion and the degree of pyramidalization of the bridgehead oxazinolactam.