278799-27-2

Basic information

• Product Name: potassium 2-(4-methoxyphenyl)-2-oxoacetate
• Synonyms: potassium 2-(4-methoxyphenyl)-2-oxoacetate
• CAS NO: 278799-27-2
• Molecular Weight: 218.25
• Mol File: 278799-27-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: potassium 2-(4-methoxyphenyl)-2-oxoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: potassium 2-(4-methoxyphenyl)-2-oxoacetate(278799-27-2)
• EPA Substance Registry System: potassium 2-(4-methoxyphenyl)-2-oxoacetate(278799-27-2)

Safety Data

• Hazardous Substances Data: 278799-27-2(Hazardous Substances Data)

Upstream product

• 4755-77-5 Ethyl oxalyl chloride 
• 100-66-3 methoxybenzene 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 7099-91-4 p-methoxybenzoylformic acid 
• 40140-16-7 ethyl (p-methoxyphenyl)oxoacetate 

Downstream Products

• 23886-71-7 4-methoxy-4'-methylbenzophenone 
• 1556678-32-0 (4-methoxyphenyl)(phenanthridine-6-yl)methanone 
• 1556678-54-6 (4-methoxyphenyl)(10-methylphenanthridin-6-yl)methanone 
• 1556678-70-6 (4-methoxyphenyl)(8-(trifluoromethyl)phenanthridin-6-yl)methanone 
• 611-94-9 4-Methoxybenzophenone 
• 22051-15-6 3-(4-methoxybenzoyl)indole 
• 22966-19-4 trans-4'-methoxychalcone 
• 37975-18-1 1-(4-bromophenyl)-3-(4-methoxyphenyl)propane-1,3-dione 
• 6327-79-3 1-(4-methoxyphenyl)-3-phenylpropane-1,3-dione 
• 1278587-88-4 N-((4-methoxyphenyl)-p-tolyl-methylene)-cyclohexylamine 

Relevant articles and documents

Synthesis of 6-acyl phenanthridines by oxidative radical decarboxylation-cyclization of α-oxocarboxylates and isocyanides

A silver catalysed synthesis of 6-acyl phenanthridines by oxidative radical decarboxylation-cyclization of α-oxocarboxylates and isocyanides was developed. This reaction provided a novel method to realize C1 insertion via a radical process and various functional groups were well-tolerated. The Royal Society of Chemistry.

Synthesis of ketones from α-oxocarboxylates and aryl bromides by Cu/Pd-catalyzed decarboxylative cross-coupling

(Chemical Equation Presented) The power of two metals: A Pd/Cu catalyst system mediates the in situ formation of acyl nucleophiles by decarboxylation of readily accessible and stable salts of α-oxocarboxylic acids and their cross-coupling with aryl or heteroaryl bromides to give ketones. The reaction may be usedin the presence of many functional groups and provides good yields.